696854
三钾5,5′,5′′-[2,2′,2′′-氯基三甲叉膦酸三(1H-苯并咪唑-2,1-二基)]戊酸
95%
别名:
(BimC4A)3
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选择尺寸
关于此项目
经验公式（希尔记法）:
C39H42K3N7O6 · xH2O
分子量:
822.09 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352200
MDL number:
Assay:
95%
Form:
solid
InChI key
QRRSLHKLVBVPSD-UHFFFAOYSA-K
SMILES string
O.[K+].[K+].[K+].[O-]C(=O)CCCCn1c(CN(Cc2nc3ccccc3n2CCCCC([O-])=O)Cc4nc5ccccc5n4CCCCC([O-])=O)nc6ccccc16
InChI
1S/C39H45N7O6.3K.H2O/c47-37(48)19-7-10-22-44-31-16-4-1-13-28(31)40-34(44)25-43(26-35-41-29-14-2-5-17-32(29)45(35)23-11-8-20-38(49)50)27-36-42-30-15-3-6-18-33(30)46(36)24-12-9-21-39(51)52;;;;/h1-6,13-18H,7-12,19-27H2,(H,47,48)(H,49,50)(H,51,52);;;;1H2/q;3*+1;/p-3
assay
95%
form
solid
reaction suitability
reaction type: click chemistry
mp
174-180 °C
Application
水溶性苯并咪唑配体对铜(I) 催化的叠氮化物-炔烃环加成（CuAAC）反应具有出色的增强作用
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Valentin O Rodionov et al.
Journal of the American Chemical Society, 129(42), 12696-12704 (2007-10-05)
Tris(2-benzimidazolylmethyl)amines have been found to be superior accelerating ligands for the copper(I)-catalyzed azide-alkyne cycloaddition reaction. Candidates bearing different benzimidazole N-substituents as well as benzothiazole and pyridyl ligand arms were evaluated by absolute rate measurements under relatively dilute conditions by aliquot
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