检测方案
98%
形式
powder
反应适用性
core: nickel
reagent type: catalyst
mp
>300 °C
SMILES字符串
Cl[Ni]Cl.COCCOC
InChI
1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
InChI key
OCMNCWNTDDVHFK-UHFFFAOYSA-L
应用
氯化镍(II)乙二醇二甲基醚络合物可用于:
- 用作外消旋苄基氯的硼化反应的催化剂,以合成对映体富集的苄基硼酸酯。
- 用作烷基碘的三氟甲基化的启动剂,以合成多种烷基CF3化合物。
- 合成双(苯并咪唑-2-亚苄基)镍钳形配合物,可用于将CO2电催化还原为CO。
- 用作路易斯酸催化剂,通过可见光的光活化作用C-酰化β-酮酸酯。
警示用语:
Danger
危险分类
Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Water-react 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Catalyst-Controlled Regioselective Acylation of ?-Ketoesters with ?-Diazo Ketones Induced by Visible Light.
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Reaction of LiOCtBu2Ph with TlPF6 forms the dimeric Tl2(OCtBu2Ph)2 complex, a rare example of a homoleptic thallium alkoxide complex demonstrating formally two-coordinate metal centers. Characterization of Tl2(OCtBu2Ph)2 by 1H and 13C NMR spectroscopy and X-ray crystallography reveals the presence of
Synthesis and comparison of nickel, palladium, and platinum bis (N-heterocyclic carbene) pincer complexes for electrocatalytic CO 2 reduction.
Dalton Transactions, 47(6), 1827-1840 (2018)
Nickel-Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles.
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商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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