跳转至内容
Merck
CN
所有图片(1)

文件

696307

Sigma-Aldrich

氯[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]铜(I)

登录查看公司和协议定价
所有图片(1)
别名:
[(iPr)CuCl], [1,3-双(2,6-二异丙基苯基)咪唑-2-亚基]氯化铜(I)
经验公式（希尔记法）:
C27H36ClCuN2
CAS号:
578743-87-0
分子量:
487.59
MDL编号:
MFCD09264276
UNSPSC代码:
12352300
PubChem化学物质编号:
329761816
NACRES:
NA.22

形式

powder

质量水平

100

反应适用性

core: copper
reagent type: catalyst

mp

>300 °C

SMILES字符串

CC(C)c1cccc(C(C)C)c1N2C=CN(\C2=[Cu]\Cl)c3c(cccc3C(C)C)C(C)C

InChI

1S/C27H36N2.ClH.Cu/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;1H;/q;;+1/p-1

InChI key

JPUFNIIPFXQOCB-UHFFFAOYSA-M

相关类别

应用

"用于烯烃和羰基的还原、卡宾转移反应、烯烃氮杂环丙化反应和醛类亚甲基化反应。"

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Hélène Lebel et al.
The Journal of organic chemistry, 72(1), 144-149 (2006-12-30)
(NHC)-Cu (NHC = N-heterocyclic carbene) complexes efficiently catalyzed the methylenation of a variety of aliphatic and aromatic aldehydes and ketones in the presence of trimethylsilyldiazomethane, triphenylphosphine, and 2-propanol. The copper catalysts are not only inexpensive compared to rhodium complexes, but
Manuel R Fructos et al.
Journal of the American Chemical Society, 126(35), 10846-10847 (2004-09-02)
The complex IPrCuCl (1) catalyzes the transfer of the :CHCO2Et group from ethyl diazoacetate (EDA) to unsaturated and saturated substrates (olefins, amine, alcohols) with very high yields. In the absence of substrate, the complex 1 does not react with EDA
Kaur H. et al.
Organometallics, 23, 1157-1157 (2004)
Barry M Trost et al.
Journal of the American Chemical Society, 128(18), 6054-6055 (2006-05-04)
New classes of nucleophiles, pyrroles, and N-methoxyamides were developed for Pd-catalyzed AAA reactions. By varying the functional groups at the 2-position of pyrroles, either regioisomer of the piperazinone is available. Using one regioisomer, the total synthesis of (+)-agelastatin A in
Valdas Jurkauskas et al.
Organic letters, 5(14), 2417-2420 (2003-07-05)
[reaction: see text] An N-heterocyclic carbene copper chloride (NHC-CuCl) complex (2) has been prepared and used to catalyze the conjugate reduction of alpha,beta-unsaturated carbonyl compounds. The combination of catalytic amounts of 2 and NaOt-Bu with poly(methylhydrosiloxane) (PMHS) as the stoichiometric

商品

N-Heterocyclic Carbene-Copper Complexes

N-Heterocyclic Carbene-Copper Complexes

N-杂环卡宾-铜络合物

设计全新的金属催化络合物时，N-杂环卡宾配体(NHCs)是绝佳选择。这些催化剂具有空气和水分稳定性，可作为前体用于合成更多空气敏感复合物。

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门