695580
1,3-丁二烯 溶液
20 wt. % in toluene
别名:
Bivinyl, Vinylethylene, alpha,gamma-Butadiene
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关于此项目
经验公式（希尔记法）:
C4H6
化学文摘社编号:
分子量:
54.09
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Form:
liquid
form
liquid
concentration
20 wt. % in toluene
refractive index
n20/D 1.493
density
0.806 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
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Application
1,3-Butadiene can be used:
- In the synthesis of 1,6-hexanedial (adipic aldehyde) by bis-hydroformylation using rhodium as a catalyst.
- As a monomer for the synthesis of cis-1,4-polybutadiene by polymerization using cobalt(II) and nickel(II) complex catalysts.
- As a precursor for the selective synthesis of butene by hydrogenation reaction.
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 1A - Flam. Liq. 2 - Muta. 1B - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-105.0 °F
flash_point_c
-76.11 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Toward the Rhodium-Catalyzed Bis-Hydroformylation of 1, 3-Butadiene to Adipic Aldehyde
Smith SE, et al.
Organometallics, 30(13), 3643-3651 (2011)
Single-atom Pd1/graphene catalyst achieved by atomic layer deposition: remarkable performance in selective hydrogenation of 1, 3-butadiene
Yan H, et al.
Journal of the American Chemical Society, 137(33), 10484-10487 (2015)
Polymerization of 1, 3-butadiene catalyzed by cobalt (II) and nickel (II) complexes bearing imino-or amino-pyridyl alcohol ligands in combination with ethylaluminum sesquichloride
Ai Pengfei, et al.
Journal of Organometallic Chemistry, 705(13), 51-58 (2012)
Dewakar Sangaraju et al.
Analytical chemistry, 84(3), 1732-1739 (2012-01-10)
1,3-Butadiene (BD) is an important industrial chemical and a common environmental pollutant present in urban air. BD is classified as a human carcinogen based on epidemiological evidence for an increased incidence of leukemia in workers occupationally exposed to BD and
Masato Ohashi et al.
Journal of the American Chemical Society, 133(45), 18018-18021 (2011-10-19)
Pyridines, which comprise one of the most important classes of the six-membered heterocyclic compounds, are widely distributed in nature, and the transition-metal-catalyzed [2 + 2 + 2] cycloaddition reaction of two alkynes and a nitrile is one of the most
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