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方案
96%
表单
solid
mp
195-209 °C
SMILES字符串
SC12BBBBBBBBBC1B2
InChI
1S/C2H12B10S/c13-2-1(3-2)4-6-8-10-12-11-9-7-5-2/h1,3-13H
InChI key
IKKUVNFZJOSSLF-UHFFFAOYSA-N
一般描述
m-Carborane-1-thiol (M1) is a boron cluster compound that is also known as icosahedral carborane thiol. It forms a self-assembled monolayer (SAM) by attaching the thiol groups with surface atoms. This SAM forms a two dimensional matrix on the metal surface that enables the tuning of surface properties such as a work function, and wettability.
应用
M1 forms a mixed SAM with m-carborane-9-thiol (M9), which is used to tune the work function of gold and silver surfaces for the fabrication of organic light emitting diodes (OLEDs).
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
?Carboranyl-cysteine??Synthesis, Structure and Self-Assembly Behavior of a Novel alpha-Amino Acid.
He T, et al.
Scientific Reports, 7(1), 16995-16995 (2017)
A coordination chemistry dichotomy for icosahedral carborane-based ligands.
Spokoyny AM, et al.
Nature Chemistry, 3(8), 590-590 (2011)
Mixed carboranethiol self-assembled monolayers on gold surfaces.
Yavuz A, et al.
Applied Surface Science, 413(1), 233-241 (2017)
Synthesis and properties of substituted icosahedral carborane thiols.
Plesek J and Stanislav H
Collection of Czechoslovak Chemical Communications, 46(3), 687-692 (1981)
Benjamin Foerster et al.
Science advances, 5(3), eaav0704-eaav0704 (2019-03-28)
The chemical nature of surface adsorbates affects the localized surface plasmon resonance of metal nanoparticles. However, classical electromagnetic simulations are blind to this effect, whereas experiments are typically plagued by ensemble averaging that also includes size and shape variations. In
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