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Merck
CN

694746

Sigma-Aldrich

双(3,5-二(三氟甲基)苯基)氯膦

别名:

P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride

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About This Item

经验公式(希尔记法):
C16H6ClF12P
分子量:
492.63
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22

表单

solid

质量水平

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

25-29 °C

官能团

phosphine

SMILES字符串

FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F

InChI

1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H

InChI key

DFZQEHBNAJGDCT-UHFFFAOYSA-N

应用

Reactant for synthesis of:
  • Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation
  • Ligands for palladium-catalyzed stereoselective allylation reactions
  • Ligands for enantioselective hydrogenations
  • Josiphos analog as catalyst for asymmetric hydrogenation
  • Ligands used in asymmetric hydrovinylation reactions

Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes

象形图

FlameCorrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B - Water-react 3

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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