形式
crystals
质量水平
旋光性
[α]20/D +222°, c = 0.5% in benzene
mp
239-241 °C (lit.)
SMILES字符串
c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
InChI
1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
InChI key
MUALRAIOVNYAIW-UHFFFAOYSA-N
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应用
(R)-BINAP 与烯丙基氯化钯 (II) 二聚体反应生成 BINAP-钯催化剂，可催化 1，3-二酮的不对称烯丙基化反应生成手性 2，2-二烷基-1，3-二酮。也可用于制备手性稳定的铑纳米粒子，可作为催化剂用于苯乙烯和醋酸乙烯酯的不对称氢甲酰化反应。
法律信息
与 Takasago 联合销售，仅供研究使用。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Asymmetric Allylation of Unsymmetrical 1, 3-Diketones Using a BINAP- Palladium Catalyst.
Kuwano R, et al.
Organic Letters, 5(12), 2177-2179 (2003)
Asymmetric Hydrogenation of 3?Oxo Carboxylates Using Binap?Ruthenium Complexes:(R)?(?)?Methyl 3?Hydroxybutanoate
Kitamura, Masato, et al.
Organic Syntheses, 1-1 (1993)
Centenary lecture. Chemical multiplication of chirality: science and applications
Noyori, Ryoji
Chemical Society Reviews, 18, 187-208 (1989)
Synthesis and resolution of the biaryl-like diphosphine (S)-Me2-CATPHOS, preparation of a derived rhodium precatalyst and applications in asymmetric hydrogenation
Doherty, Simon, and Catherine H. Smyth
Nature Protocols, 7.10, 1884-1896 (2012)
RuHCl (diphosphine)(diamine): Catalyst Precursors for the Stereoselective Hydrogenation of Ketones and Imines1
Abdur-Rashid, Kamaluddin, Alan J. Lough, and Robert H. Morris
Organometallics, 20.6, 1047-1049 (2001)
商品
We present an article concerning BINAP/SEGPHOS® Ligands and Complexes.
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
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