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Merck
CN

689963

Sigma-Aldrich

苯甲酰乙酸乙酯

Arxada quality, ≥98% (GC)

别名:

3-氧代苯丙酸乙酯, 苄酸乙酸乙酯

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About This Item

线性分子式:
C6H5COCH2COOC2H5
CAS号:
分子量:
192.21
Beilstein:
389944
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

6.6 (vs air)

质量水平

检测方案

≥98% (GC)

形式

liquid

质量

Arxada quality

制造商/商品名称

Arxada AG

折射率

n20/D 1.52 (lit.)

bp

265-270 °C (lit.)

密度

1.11 g/mL at 25 °C (lit.)

SMILES字符串

CCOC(=O)CC(=O)c1ccccc1

InChI

1S/C11H12O3/c1-2-14-11(13)8-10(12)9-6-4-3-5-7-9/h3-7H,2,8H2,1H3

InChI key

GKKZMYDNDDMXSE-UHFFFAOYSA-N

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应用

Ethyl benzoylacetate is a general reagent used in the synthesis of substituted pyrroles, oxazoles, indoles, imidazo[1, 2-a] pyridines and a variety of other aromatic compounds.

WGK

WGK 2

闪点(°F)

284.0 °F

闪点(°C)

140 °C

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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Rhenium-and manganese-catalyzed synthesis of aromatic compounds from 1, 3-dicarbonyl compounds and alkynes.
Kuninobu Y, et al.
The Journal of Organic Chemistry, 75(2), 334-341 (2009)
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers.
Jiang Y, et al.
Journal of the American Chemical Society, 134(9), 4104-4107 (2012)
Facile synthesis of polysubstituted oxazoles via a copper-catalyzed tandem oxidative cyclization.
Wan C, et al.
Organic Letters, 12(10), 2338-2341 (2010)
Facile access to polysubstituted indoles via a cascade Cu-catalyzed arylation? condensation process.
Chen Y, et al.
The Journal of Organic Chemistry, 72(24), 9329-9334 (2007)
TBAI-catalyzed oxidative coupling of aminopyridines with β-keto esters and 1, 3-diones?synthesis of imidazo [1, 2-a] pyridines.
Ma L, et al.
Chemical Communications (Cambridge, England), 47(40), 11333-11335 (2011)

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