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Merck
CN

689386

Sigma-Aldrich

甲醛二丁基缩醛

puriss., ≥97.0% (GC)

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别名:
Butylal, Dibutoxymethane
线性分子式:
CH2(OCH2CH2CH2CH3)2
CAS号:
分子量:
160.25
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

等级

puriss.

质量水平

检测方案

≥97.0% (GC)

形式

liquid

杂质

≤0.25% water

折射率

n20/D 1.406

密度

0.835 g/mL at 20 °C

SMILES字符串

CCCCOCOCCCC

InChI

1S/C9H20O2/c1-3-5-7-10-9-11-8-6-4-2/h3-9H2,1-2H3

InChI key

QLCJOAMJPCOIDI-UHFFFAOYSA-N

相关类别

一般描述

Formaldehyde dibutyl acetal is an acetal used in the manufacture of synthetic resins, antiseptics, deodorants, and fungicides. It is also used as a fuel additive to increase the octane number of gasoline or the n-cetane number of diesel fuels and reduce smoke and particulate emissions.

应用

Formaldehyde dibutyl acetal is a halogen-free and less toxic solvent that can be used to solubilize commercial low-density polyethylene (LDPE) samples to analyze molecular weight distribution using gel permeation chromatography (GPC). It can also be used as a reactant to prepare butoxymethyltriphenylphosphonium iodide, which is used for carbon homologation and also as a useful key intermediate in organic synthesis.

WGK

WGK 1

闪点(°F)

143.6 °F

闪点(°C)

62 °C

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Facile synthesis of α-alkoxymethyltriphenylphosphonium iodides: new application of PPh 3/I 2
Gondal HY, et al.
Chemistry Central Journal, 12(1), 1-10 (2018)
Selected physicochemical properties of dibutoxymethane
P-T Marcela and Szafranski AM
Journal of Chemical and Engineering Data, 45(6), 988-990 (2000)
Characterization of low-density polyethylene in dibutoxymethane by high-temperature gel permeation chromatography with triple detection
Boborodea A, et al.
Chromatographia, 79(15), 971-976 (2016)
Vieille-Petit, L.; et al.
Chemical Communications (Cambridge, England), 3783-3783 (2009)
Xinjun Luan et al.
Journal of the American Chemical Society, 130(21), 6848-6858 (2008-05-01)
A new class of easily accessible and stable imidazolin-2-ylidenes has been synthesized where the side chains are comprised of substituted naphthyl units. Introduction of the naphthyl groups generates C 2 -symmetric ( rac) and C s- symmetric ( meso) atropisomers

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