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方案
97%
表单
solid
反应适用性
reagent type: reductant
mp
131-135 °C
官能团
amine
hydrazide
nitro
SMILES字符串
C\C(C)=N\NS(=O)(=O)c1ccccc1[N+]([O-])=O
InChI
1S/C9H11N3O4S/c1-7(2)10-11-17(15,16)9-6-4-3-5-8(9)12(13)14/h3-6,11H,1-2H3
InChI key
SBNYNTYNEJTMQO-UHFFFAOYSA-N
应用
用于烯丙基置换反应和醇类还原反应的试剂，也可用于烯丙基碳酸酯和乙烯基环氧化物的立体选择性温和还原反应。
IPNBSH A Reagent for the Simple Reduction of Alcohols
Reactant for synthesis of:
Reacts with di-Me phosphonate
Reactant for synthesis of:
- (-)-Acylfulvene and (-)-irofulven for use as antitumor agents
- Bicycloundecadienones and bicyclodecadienones via carbonylative cycloaddition
- Monoalkyldiazenes for allylic reduction
Reacts with di-Me phosphonate
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction.
Mohammad Movassaghi et al.
Angewandte Chemie (International ed. in English), 47(46), 8909-8912 (2008-10-17)
Mohammad Movassaghi et al.
The Journal of organic chemistry, 72(5), 1838-1841 (2007-02-06)
The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates accessed by sequential Mitsunobu displacement, hydrolysis, and fragmentation under mild reaction conditions.
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