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方案
95%
表单
powder
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
99-106 °C
官能团
phosphine
SMILES字符串
CC1(C)O[PH](=O)OC1(C)C
InChI
1S/C6H13O3P/c1-5(2)6(3,4)9-10(7)8-5/h10H,1-4H3
InChI key
QPONEGYFSLRCLJ-UHFFFAOYSA-N
应用
在空气中稳定的前配体，用于钯催化的 Kumada 型交叉偶联反应。
- Preligand in palladium-catalyzed Kumada cross-coupling reactions of aryl tosylates with Grignard reagents
- Catalyst for reversible chain transfer polymerizations
Reactant for:
- Synthesis of oxapalladacycle as catalyst for Markovnikov-type addition
- Preparation of palladium(II) complexes as catalysts for Heck cross-coupling reactions
- Preparation of palladium catalysts for asymmetric hydrogenation of a-keto phosphonates
- Hydrophosphorylation of alkenes, dienes and enynes in the presence of rhodium catalysts
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Dermal - Eye Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Lutz Ackermann et al.
Organic letters, 8(16), 3457-3460 (2006-07-28)
[reaction: see text] Air-stable and easily accessible PinP(O)H enables highly efficient palladium-catalyzed Kumada cross-coupling reactions of aryl tosylates. The in situ generated catalyst proved applicable not only to electron-rich and electron-poor carbocyclic tosylates but also to heterocyclic tosylates, such as
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