InChI
1S/C32H28N.2CO.ClH.Ru/c1-23(2)33-32-30(26-19-11-5-12-20-26)28(24-15-7-3-8-16-24)29(25-17-9-4-10-18-25)31(32)27-21-13-6-14-22-27;2*1-2;;/h3-23,33H,1-2H3;;;1H;/q;;;;+1/p-1
InChI key
BRMXQWNTLPPMGQ-UHFFFAOYSA-M
SMILES string
[Cl-].[Ru+].[C-]#[O+].[C-]#[O+].CC(C)N[C]1[C]([C]([C]([C]1c2ccccc2)c3ccccc3)c4ccccc4)c5ccccc5
assay
96%
form
powder
reaction suitability
core: ruthenium, reagent type: catalyst
Application
用于与酶共同作用，通过动态动力学拆分来催化不对称转化的金属催化剂。
Catalyst for asymmetric:
Reactant for synthesis of air-stable racemization catalysts
Racemization catalyst for dynamic kinetic resolution of secondary alcohols
- Synthesis of achaetolide
- Transfer hydrogenation and racemization
- Total synthesis of stagonolide-C
Reactant for synthesis of air-stable racemization catalysts
Racemization catalyst for dynamic kinetic resolution of secondary alcohols
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Mahn-Joo Kim et al.
Journal of the American Chemical Society, 125(38), 11494-11495 (2003-09-18)
A new procedure for the dynamic kinetic resolution (DKR) of racemic alcohols into single enantiomers is described. This procedure employs surfactant-treated subtilisin as an (S)-selective resolving catalyst and an aminocyclopentadienylruthenium complex as a racemizing catalyst. The DKR is performed best
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