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Merck
CN

686069

Titanium hydride

greener alternative

hydrogen-storage grade

别名:

Titanium dihydride, Titanium(II) hydride

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关于此项目

线性分子式:
TiH2
化学文摘社编号:
分子量:
49.88
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
231-726-8
MDL number:
Grade:
hydrogen-storage grade
Form:
powder
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产品名称

二氢化钛, hydrogen-storage grade

InChI key

COEYXIBLSAIEKV-UHFFFAOYSA-N

InChI

1S/Ti.2H

SMILES string

[H][Ti][H]

grade

hydrogen-storage grade

form

powder

autoignition temp.

437 °F

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>400 °C (dec.)

density

3.91 g/mL at 25 °C (lit.)

greener alternative category

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

TiH2 was used as intermetallic precursor for the preparation of Ti3AlC2 by self-propagating high temperature synthesis (SHS).1 TiH2 may be added to MgH2 to decrease the enthalpy and entropy of the absorption and desorption of hydrogen.
Titanium(II) hydride (TiH2) is a non-stoichiometric compound that can be used in the enhancement of fracture by localized plastic deformation and brittle fracture for titanium and titanium alloy. It can be used in the hydrogen evolution and hydrogen storage. It can also be used in the foaming of aluminum due to its decomposition temperature closer to aluminum′s melting point.

Analysis Note

可索取 X 射线衍射图和金属纯度数据。

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Sol. 1

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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High ramp rate thermogravimetric analysis of zirconium (II) hydride and titanium (II) hydride
Licavoli JJ and Sanders PG
Thermochimica Acta, 616(43), 1-8 (2015)
Mechanical properties of titanium hydride
Xu JJ, et al.
Journal of alloys and compounds, 436(1-2), 82-85 (2007)
Hydrogen storage properties of nanosized MgH2- 0.1 TiH2 prepared by ultrahigh-energy- high-pressure milling
Lu J, et al.
Journal of the American Chemical Society, 131(43), 15843-15852 (2009)
The Mechanical Properties of Compact Titanium Produced from Titanium Hydride Powders Using Self-Propagating High-Temperature Synthesis
Dekhtyar AI, et al.
Powder Metallurgy and Metal Ceramics, 53(9-10), 549-556 (2015)
Effect of Ti intermetallic catalysts on hydrogen storage properties of magnesium hydride
Zhou C, et al.
The Journal of Physical Chemistry, 117(25), 12973-12980 (2013)

商品

Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids

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