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Merck
CN

686034

Sigma-Aldrich

氢化锂铝

greener alternative

hydrogen-storage grade

别名:

LAH, 丙氨酸锂, 四氢铝酸锂

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About This Item

线性分子式:
LiAlH4
CAS号:
分子量:
37.95
EC 号:
MDL编号:
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.23

等级

hydrogen-storage grade

质量水平

方案

>99.95%

表单

pellets

反应适用性

reagent type: reductant

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

125 °C (dec.) (lit.)

环保替代产品分类

SMILES字符串

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

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一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

应用

Lithium aluminum hydride (LAH) is majorly used in hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).

分析说明

可按要求提供氢含量、XRD 谱图和金属纯度数据。

象形图

FlameCorrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1A - Water-react 1

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Lithium aluminum hydride as reducing agent for chemically reduced graphene oxides
Ambrosi A, et al.
Chemistry of Materials, 24(12), 2292-2298 (2012)
Regeneration of lithium aluminum hydride
Graetz J, et al.
Journal of the American Chemical Society, 130(52), 17790-17794 (2008)
A first-principles study of the electronic structure and stability of a lithium aluminum hydride for hydrogen storage
Song Y, et al.
The Journal of Physical Chemistry B, 110(13), 6906-6910 (2006)
Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6
Chen J, et al.
The Journal of Physical Chemistry B, 105(45), 11214-11220 (2001)
Sonja Stanković et al.
Organic & biomolecular chemistry, 8(19), 4266-4273 (2010-08-05)
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corresponding beta-amino alcohols, which were then used as eligible substrates in the synthesis of 5-methylmorpholin-2-ones via condensation

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