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安全信息

686026

Sigma-Aldrich

硼氢化锂

greener alternative

hydrogen-storage grade, ≥90%

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About This Item

线性分子式:
LiBH4
CAS号:
16949-15-8
分子量:
21.78
EC 号:
241-021-7
MDL编号:
MFCD00011088
UNSPSC代码:
26111700
PubChem化学物质编号:
329761014
NACRES:
NA.23

等级

hydrogen-storage grade

质量水平

100

方案

≥90%

表单

crystals

反应适用性

reagent type: reductant

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275 °C (dec.)

密度

0.666 g/mL at 25 °C (lit.)

环保替代产品分类

, Enabling

SMILES字符串

[Li+].[BH4-]

InChI

1S/BH4.Li/h1H4;/q-1;+1

InChI key

UUKMSDRCXNLYOO-UHFFFAOYSA-N

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相关类别

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

应用

Lithium borohydride (LiBH4) is a complex hydride with a high hydrogen density. It is a strong reducing agent and an electrode material. It has a high gravimetric (18.4 wt%) and volumetric (121 kg/m3) hydrogen storage capacities. It can also be used in lithium-ion batteries.

分析说明

可按要求提供氢含量、XRD 谱图和金属纯度数据。

警示用语：

Danger

危险声明

H260,H301,H314

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react 1

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBQ6470
SHBF7136V
SHBB4436V
21898PJ
00112JH

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Effects of intermediate layer on interfacial resistance for all-solid-state lithium batteries using lithium borohydride
Takahashi K, et al.
Solid State Ionics, 262, 179-182 (2014)
Hydrogen storage properties of modified lithium borohydrides
Au M, et al.
Journal of alloys and compounds, 462(1-2), 303-309 (2008)
Nanoconfined 2LiBH4-MgH2-TiCl3 in carbon aerogel scaffold for reversible hydrogen storage
Gosalawit-Utke R, et al.
International Journal of Hydrogen Energy, 38(8), 3275-3282 (2013)
Mita Dasog et al.
Chemical communications (Cambridge, England), 47(30), 8569-8571 (2011-06-28)
In the presence of large excesses of borohydride salts, gold monolayer protected-clusters can be grown to larger sizes simply by controlling the amount of reducing agent added to smaller clusters. In addition, gold monolayer clusters can be used as catalysts
Barbara Milani et al.
Dalton transactions (Cambridge, England : 2003), (34)(34), 4659-4663 (2008-11-26)
Transfer hydrogenation from 2-propanol to CO/4-methylstyrene and CO/styrene polyketones was catalyzed by [Ir(diene)(N-N)X] (N-N = nitrogen chelating ligand; X = halogen) in the presence of a basic cocatalyst. The reactions were performed using dioxane as cosolvent, in order to overcome
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