所有图片(1)
About This Item
线性分子式:
[ReBr(CO)3(C4H8O)]2
CAS号:
分子量:
844.49
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
表单
powder
反应适用性
core: rhenium
reagent type: catalyst
SMILES字符串
Br[Re].Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1CCOC1.C2CCOC2
InChI
1S/2C4H8O.6CO.2BrH.2Re/c2*1-2-4-5-3-1;6*1-2;;;;/h2*1-4H2;;;;;;;2*1H;;/q;;;;;;;;;;2*+1/p-2
InChI key
GARJHXMUDDMPBU-UHFFFAOYSA-L
应用
用于将乙炔插入 1,3-二羰基以及合成异苯并呋喃的催化剂。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Yoichiro Kuninobu et al.
Journal of the American Chemical Society, 128(38), 12376-12377 (2006-09-21)
A rhenium complex, [ReBr(CO)3(thf)]2, catalyzed reactions of aromatic ketimines with aldehydes to give isobenzofuran derivatives in good to excellent yields. In contrast to ruthenium and rhodium catalysts, aldehydes, which are polar unsaturated molecules, inserted into the C-H bond after activation
Takai, K. et al.
Journal of the American Chemical Society, 128, 11369-11369 (2006)
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