所有图片(4)
About This Item
线性分子式:
[Ir(OCH3)(C8H12)]2
CAS号:
分子量:
662.86
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
![[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)](/deepweb/assets/sigmaaldrich/product/structures/130/734/8846aa26-1858-458a-998d-8c306c13bf0f/640/8846aa26-1858-458a-998d-8c306c13bf0f.png)
表单
crystals
质量水平
反应适用性
core: iridium
reagent type: catalyst
reaction type: C-H Activation
mp
154-179 °C (D)
储存温度
−20°C
SMILES字符串
C[O+]1[Ir-]2[O+](C)[Ir-]12.C3CC=CCCC=C3.C4CC=CCCC=C4
InChI
1S/2C8H12.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*+1;2*-1/b2*2-1-,8-7-;;;;
InChI key
BGWIAAATAAWGOI-MIXQCLKLSA-N
应用
用作以下反应的催化剂：
- 制备杂芳基稠合的吲哚环体系，作为HCV NS5B聚合酶的抑制剂
- 硼化反应/Suzuki-Miyaura偶联反应
- Metalation-Suzuki交叉偶联反应，用于合成联芳基和杂双芳基
- 四硼化反应
- 高度区域和对映选择性不对称硼氢化
- 通过C-H活化使芳基酮、苯甲醛和苄醇衍生物发生邻甲硅烷基化
一种强大的C-H活化催化剂，用于从芳烃制备酚
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Ir?Catalyzed Borylation of C H Bonds in N?Containing Heterocycles: Regioselectivity in the Synthesis of Heteroaryl Boronate Esters.
Mkhalid I, et al.
Angewandte Chemie (International Edition in English), 45(3), 489-491 (2006)
A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen) CuRF].
Litvinas N, et al.
Angewandte Chemie (International Edition in English), 51(2), 536-539 (2012)
Catalytic functionalization of unactivated primary C?H bonds directed by an alcohol.
Simmons E, et al.
Nature, 483(7387), 70-70 (2012)
Direct C?H borylation and C?H arylation of pyrrolo [2, 3-d] pyrimidines: synthesis of 6, 8-disubstituted 7-deazapurines.
Klecka M, et al.
Organic & Biomolecular Chemistry, 7(5), 866-868 (2009)
Robert E Maleczka et al.
Journal of the American Chemical Society, 125(26), 7792-7793 (2003-06-26)
An efficient one-pot C-H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bearing ortho-/para-directing groups, as such substrates are difficult to access by other phenol syntheses.
商品
Arylboronic acids and esters, vital tools in chemical transformations, find extensive use, particularly in the Suzuki-Miyaura cross-coupling reaction.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门