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Merck
CN

684821

二乙酸-1,2-双(苯亚磺酰)乙基钯(II)

greener alternative

powder

别名:

White 催化剂

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关于此项目

经验公式(希尔记法):
C18H20O6PdS2
化学文摘社编号:
分子量:
502.90
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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产品名称

二乙酸-1,2-双(苯亚磺酰)乙基钯(II),

SMILES string

CC(=O)O[Pd]OC(C)=O.O=S(CCS(=O)c1ccccc1)c2ccccc2

InChI

1S/C14H14O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;2*1-2(3)4;/h1-10H,11-12H2;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

SNNYSJNYZJXIFE-UHFFFAOYSA-L

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
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Greener Alternative Product

greener alternative category

storage temp.

−20°C

Quality Level

Application

Catalyst for allylic C-H oxidation, useful for preparation of branched allylic esters, macrocycles, and amino alcohol derivatives.

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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syn-1,2-Amino alcohols via diastereoselective allylic C-H amination.
Kenneth J Fraunhoffer et al.
Journal of the American Chemical Society, 129(23), 7274-7276 (2007-05-23)
Kenneth J Fraunhoffer et al.
Journal of the American Chemical Society, 128(28), 9032-9033 (2006-07-13)
A novel Pd/sulfoxide-catalyzed macrolactonization reaction of linear omega-alkenoic acids is reported that proceeds via serial ligand-catalyzed allylic C-H oxidation. The scope of this macrolactonization appears to be very broad. Aryl, alkyl, and (Z)-alpha,beta-unsaturated acids are all competent nucleophiles for this

商品

The "White catalyst" by Professor M. Christina White enables allylic carbon functionalization, demonstrating exceptional catalytic activity.

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