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683345

Sigma-Aldrich

[Pd2(dba)3] x dba

Umicore

别名:

三(二亚苄基丙酮)二钯(0), Pd2dba3, Pd2(dba)3

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About This Item

线性分子式:
(C6H5CH=CHCOCH=CHC6H5)3Pd2
CAS号:
51364-51-3
分子量:
915.72
MDL编号:
MFCD00013310
UNSPSC代码:
12161600
PubChem化学物质编号:
329760813
NACRES:
NA.22

质量水平

200

表单

powder

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

152-155 °C (lit.)

储存温度

2-8°C

SMILES字符串

[Pd].[Pd].O=C(\C=C\c1ccccc1)/C=C/c2ccccc2.O=C(\C=C\c3ccccc3)/C=C/c4ccccc4.O=C(\C=C\c5ccccc5)/C=C/c6ccccc6

InChI

1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;

InChI key

CYPYTURSJDMMMP-WVCUSYJESA-N

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相关类别

应用

用于不对称和交叉耦合催化的Umicore预催化剂

C-C和C-N键的形成的催化剂，尤其是Suzuki，Heck偶联反应

法律信息

Umicore 产品

其他信息请见www.pmc.umicore.com

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说明
价格

象形图

Exclamation markEnvironment
GHS07,GHS09

警示用语：

Warning

危险声明

H317,H411

危险分类

Aquatic Chronic 2 - Skin Sens. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL6659
BCCH0119
BCCH7416
BCCG0390
BCCF7787

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Michael J Ardolino et al.
Tetrahedron, 71(37), 6409-6413 (2015-08-19)
While Pd-catalyzed allyl-allyl cross-couplings in the presence of small-bite-angle bidentate ligands reliably furnish the branched regioisomer with high levels of selectivity, cross-couplings in the presence of large-bite-angle bidentate ligands give varying, often unpredictable, levels of selectivity. In a combined computational
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Journal of labelled compounds & radiopharmaceuticals, 57(8), 540-549 (2014-07-06)
The nucleosides zidovudine (AZT), stavudine (d4T), and telbivudine (LdT) are approved for use in the treatment of human immunodeficiency virus (HIV) and hepatitis B virus (HBV) infections. To promote positron emission tomography (PET) imaging studies on their pharmacokinetics, pharmacodynamics, and

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