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Merck
CN

683213

Chiralyst P374

greener alternative

97%, Umicore, powder

别名:

二氯(p-甲基异丙苯)钌(II) 二聚体, 二(μ-氯)二氯双(对-异丙苯)二钌(II), (对伞花烃)钌二氯二聚体, 苯，1-甲基-4-(1-甲基乙基)- ，钌络合物

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关于此项目

线性分子式:
[Ru(p-cymene)Cl2]2
化学文摘社编号:
52462-29-0
分子量:
612.39
UNSPSC Code:
12161600
PubChem Substance ID:
329760807
NACRES:
NA.22
MDL number:
MFCD00064793

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产品名称

Chiralyst P374, Umicore, 97%

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2

InChI

1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

LAXRNWSASWOFOT-UHFFFAOYSA-J

assay

97%

form

powder

reaction suitability

core: ruthenium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

247.0-250.0 °C (dec.) (lit.)

greener alternative category

Aligned

Quality Level

100

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相关类别

Application

硅氢化催化剂
用于不对称和交叉耦合催化的Umicore预催化剂
环金属化钌与芳基亚胺和含氮杂环通过C-H键活化发生络合反应

Legal Information

Umicore 产品

更多信息请参见 www.pmc.umicore.com

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCG6187
BCCC5798
BCBZ8007
BCBV0070
BCBR4315V

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Bin Li et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)

商品

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

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