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![(R)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-联萘-2,2′-二基磷酸氢酯 95%](/deepweb/assets/sigmaaldrich/product/structures/270/636/14dc9413-bcb4-478c-8e4d-3605317c13a5/640/14dc9413-bcb4-478c-8e4d-3605317c13a5.png)
![双(1,5-环辛二烯)四[双(3,5-三氟甲基)苯基]硼酸铑(I)](/deepweb/assets/sigmaaldrich/product/structures/275/399/3f196135-3b90-4f6f-95b0-512766f1f5e1/640/3f196135-3b90-4f6f-95b0-512766f1f5e1.png)
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应用
双（降冰片二烯）铑(I) 四氟硼酸可用作催化剂来合成以下物质：
- 通过芳基硼酸的1,4加成形成丁烯羟酸内酯
- 手性β芳基取代的酮和酯。
- β-由 β-芳氧基α,γ-不饱和酯形成芳氧基碳酸酯。
法律信息
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Determination of the absolute configuration of two ?v?6 integrin inhibitors for the treatment of idiopathic pulmonary fibrosis and investigations on the asymmetric 1, 4-addition of arylboronic acids to crotonate esters bearing a C4-oxygen substituent
Procopiou PA, et al.
Tetrahedron Asymmetry, 28(10), 1384-1393 (2017)
Enantioselective Synthesis of ?-Aryloxycarboxylic Esters via Asymmetric Hydrogenation of ?-Aryloxy-?, ?-Unsaturated Esters
Stewart GW, et al.
Organic Letters, 14(21), 5440-5443 (2012)
Practical method for asymmetric addition of arylboronic acids to ?, ?-unsaturated carbonyl compounds utilizing an in situ prepared rhodium catalyst
Lukin K, et al.
The Journal of Organic Chemistry, 74(2), 929-931 (2008)
商品
Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.
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