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![(R)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-联萘-2,2′-二基磷酸氢酯 95%](/deepweb/assets/sigmaaldrich/product/structures/270/636/14dc9413-bcb4-478c-8e4d-3605317c13a5/640/14dc9413-bcb4-478c-8e4d-3605317c13a5.png)
![双(1,5-环辛二烯)四[双(3,5-三氟甲基)苯基]硼酸铑(I)](/deepweb/assets/sigmaaldrich/product/structures/275/399/3f196135-3b90-4f6f-95b0-512766f1f5e1/640/3f196135-3b90-4f6f-95b0-512766f1f5e1.png)
![(S,R,R)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)二(1-苯基乙基)胺 95% (HPLC)](/deepweb/assets/sigmaaldrich/product/structures/366/790/7555ef31-5d0b-45c9-ad40-5dfd0fe85125/640/7555ef31-5d0b-45c9-ad40-5dfd0fe85125.png)
应用
双（降冰片二烯）铑(I) 四氟硼酸可用作催化剂来合成以下物质：
- 通过芳基硼酸的1,4加成形成丁烯羟酸内酯
- 手性β芳基取代的酮和酯。
- β-由 β-芳氧基α,γ-不饱和酯形成芳氧基碳酸酯。
法律信息
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Practical method for asymmetric addition of arylboronic acids to ?, ?-unsaturated carbonyl compounds utilizing an in situ prepared rhodium catalyst
Lukin K, et al.
The Journal of Organic Chemistry, 74(2), 929-931 (2008)
Determination of the absolute configuration of two ?v?6 integrin inhibitors for the treatment of idiopathic pulmonary fibrosis and investigations on the asymmetric 1, 4-addition of arylboronic acids to crotonate esters bearing a C4-oxygen substituent
Procopiou PA, et al.
Tetrahedron Asymmetry, 28(10), 1384-1393 (2017)
Enantioselective Synthesis of ?-Aryloxycarboxylic Esters via Asymmetric Hydrogenation of ?-Aryloxy-?, ?-Unsaturated Esters
Stewart GW, et al.
Organic Letters, 14(21), 5440-5443 (2012)
商品
Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.
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