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Merck
CN

682527

6-(二茂铁基)己硫醇

别名:

FHT, 6-(巯基己基)二茂铁

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关于此项目

经验公式(希尔记法):
C16H22FeS
化学文摘社编号:
分子量:
302.26
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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InChI

1S/C11H17S.C5H5.Fe/c12-10-6-2-1-3-7-11-8-4-5-9-11;1-2-4-5-3-1;/h4-5,8-9,12H,1-3,6-7,10H2;1-5H;

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.SCCCCCC[C]2[CH][CH][CH][CH]2

InChI key

YENJERDZPAXYRX-UHFFFAOYSA-N

bp

321-353 °C

Quality Level

General description

6-(二茂铁基)己硫醇(FHT)是二茂铁基链烷硫醇,可形成自组装单层(SAM),其中二茂铁基键合可促进涂层与基底之间的电子交换。

Application

FHT可用作金基底上的SAM,作为电子传输介质,或能应用于生物电化学设备。FHT还可以形成金-硫醇键,官能化石墨烯涂层的金表面,用作电子转移介体。
这种材料的单分子层易于制造,并提供稳定和可重复的系统,并用于检测分子间的相互作用。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

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Rebecca L Stiles et al.
Journal of the American Chemical Society, 130(6), 1856-1865 (2008-01-18)
Au nanoparticles fully coated with omega-ferrocenyl hexanethiolate ligands, with average composition Au225(omega-ferrocenyl hexanethiolate)43, exhibit a unique combination of adsorption properties on Pt electrodes. The adsorbed layer is so robust that electrodes bearing submonolayer, monolayer, and multilayer quantities of these nanoparticles
Kinetic modulation of outer-sphere electron transfer reactions on graphene electrode with a sub-surface metal substrate.
Hui J, et al.
Electrochimica Acta, 211(1-2), 1016-1023 (2016)
Damian J Matuszewski et al.
PloS one, 12(11), e0188496-e0188496 (2017-12-01)
The choice of an optimal feature detector-descriptor combination for image matching often depends on the application and the image type. In this paper, we propose the Log-Polar Magnitude feature descriptor-a rotation, scale, and illumination invariant descriptor that achieves comparable performance
Fabian Fool et al.
IEEE transactions on ultrasonics, ferroelectrics, and frequency control, 66(2), 297-308 (2018-12-12)
An ultrasound scan generates a huge amount of data. To form an image, this data has to be transferred to the imaging system. This is an issue for applications where the data transfer capacity is limited such as hand-held systems
An integrated experimental-theoretical approach to understand the electron transfer mechanism of adsorbed ferrocene-terminated alkanethiol monolayers.
Stragliotto M, et al.
Electrochimica Acta, 265(1-2), 303-315 (2018)

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