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682373

Hoveyda-Grubbs 催化剂® M721

greener alternative

Umicore, solid

别名:

Hoveyda-Grubbs 催化剂® M72 SI(o-Tol) (C571), Stewart-Grubbs 催化剂, 二氯[1,3-双(2-甲基苯基)-2-咪唑烷亚基](2-异丙氧基苯亚甲基)钌(II)

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关于此项目

经验公式（希尔记法）:
C27H30Cl2N2ORu
化学文摘社编号:
927429-61-6
分子量:
570.52
UNSPSC Code:
12161600
PubChem Substance ID:
24885712
NACRES:
NA.22
MDL number:
MFCD09265166
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产品名称

Hoveyda-Grubbs 催化剂® M721, Umicore

Quality Level

100

product line

Grubbs Catalyst® M700 Series

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Ring-Opening Polymerization

manufacturer/tradename

Umicore Grubbs Catalyst® M700 Series

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

199-208 °C

greener alternative category

Aligned

storage temp.

2-8°C

SMILES string

CC(C)Oc1ccccc1C=[Ru](Cl)(Cl)=C2N(CCN2c3ccccc3C)c4ccccc4C

InChI

1S/C17H18N2.C10H12O.2ClH.Ru/c1-14-7-3-5-9-16(14)18-11-12-19(13-18)17-10-6-4-8-15(17)2;1-8(2)11-10-7-5-4-6-9(10)3;;;/h3-10H,11-12H2,1-2H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2

InChI key

ZDJCARGGZRTYFH-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a highly active ruthenium-based olefin metathesis catalyst, more stable than standard Grubbs catalysts due to a chelating benzylidene ligand. Click here for more information.
详细了解我们的复分解反应催化剂。

Application

Hoveyda-Grubbs 催化剂 ® 2 代的无空间位阻类似物。空间位阻烯烃的闭环复分解反应。也可用于含大烯丙基取代基的烯烃的交叉复分解。

Other Notes

Aldrich 用于烯烃复分解反应的 Grubbs 催化剂® 技术

Legal Information

Umicore 产品

产品许可证
该产品及其制造或使用受Umicore PMC拥有或控制的一项或多项已发布或正在申请的美国专利（和国外等同专利）权限管辖。通过Sigma-Aldrich、其关联公司或其授权分销商从Umicore PMC购买此产品，购买者将享受有限的一次性、非排他、不可转让、不可分配的许可。购买者使用此产品可能会侵犯第三方拥有或控制的专利。购买者应自行确保其使用产品未侵犯第三方专利权或超出本协议授予的许可范围。

有关产品的更多信息，请询当地Umicore PMC联系人，网址http://www.pmc.umicore.com。
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW9975
MKCM6292
MKCQ7600
MKCP8091
MKCP0044

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相关内容

Grubbs Group – Prof. Product Portal

Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.

Olefin Metathesis Application Guide

The Olefin Application Metathesis Application Guide provides - The Key Features of Metathesis, General Reaction Procedures, Guidance for Choosing the Correct Metathesis Route, A Metathesis Quick Guide

David E White et al.
Journal of the American Chemical Society, 130(3), 810-811 (2008-01-01)
Described in this report is the first total synthesis of elatol, a halogenated sesquiterpene in the chamigrene natural product family. The key disconnections in our synthetic approach include an enantioselective decarboxylative allylation to form the all-carbon quaternary stereocenter and a
Ian C Stewart et al.
Organic letters, 9(8), 1589-1592 (2007-03-24)
[reaction: see text] A series of ruthenium-based metathesis catalysts with N-heterocyclic carbene (NHC) ligands have been prepared in which the N-aryl groups have been changed from mesityl to mono-ortho-substituted phenyl (e.g., tolyl). These new catalysts offer an exceptional increase in
Schrodi, Y.; Pederson, R.L.
Aldrichimica Acta, 40, 45-45 (2007)

全球贸易项目编号

货号GTIN
682373-100MG04061832754970
682373-500MG04061832754987
682373-2G04061833555101