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Merck
CN

682365

Grubbs催化剂® M207

Umicore, solid

别名:

二氯[1,3-双(2,4,6-三甲基苯基)-2-咪唑烷亚基](3-甲基-2-亚丁烯基)(三环己基膦)钌(II), Grubbs催化剂® M2b (C827), [SIMes]二氯(3-甲基-2-亚丁烯基)(三环己基膦)Ru(II), 异亚戊烯基(1,3-双(2,4,6-三甲基苯基)-咪唑烷-2-亚基)(三环己基膦)二氯化钌(II)

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关于此项目

经验公式（希尔记法）:
C44H67Cl2N2PRu
化学文摘社编号:
253688-91-4
分子量:
826.97
UNSPSC Code:
12161600
PubChem Substance ID:
24885711
NACRES:
NA.22
MDL number:
MFCD09265165

主要文件

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产品名称

Grubbs催化剂® M207, Umicore

SMILES string

C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C\C(C)=C/C=[Ru](Cl)(Cl)=C4N(CCN4c5c(C)cc(C)cc5C)c6c(C)cc(C)cc6C

InChI

1S/C21H26N2.C18H33P.C5H8.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4-5(2)3;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2

InChI key

LCOFYVWULBZOTA-UHFFFAOYSA-L

reaction suitability

core: ruthenium
reagent type: catalyst
core: ruthenium
reaction type: Olefin Metathesis

storage temp.

2-8°C

Quality Level

100

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相关类别

Application

一种通用烯烃复分解催化剂，其反应活性与2nd代格拉布斯催化剂®相似。

General description

详细了解我们的复分解反应催化剂。

Legal Information

Umicore产品

产品许可证
该产品及其制造或使用受Umicore PMC拥有或控制的一项或多项已发布或正在申请的美国专利（和国外等同专利）权限管辖。通过Sigma-Aldrich、其关联公司或其授权分销商从Umicore PMC购买此产品，购买者将享受有限的一次性、非排他、不可转让、不可分配的许可。购买者使用此产品可能会侵犯第三方拥有或控制的专利。购买者应自行确保其使用产品未侵犯第三方专利权或超出本协议授予的许可范围。

有关产品的更多信息，请询当地Umicore PMC联系人，网址http://www.pmc.umicore.com。
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Other Notes

Aldrich用于烯烃复分解反应的Grubbs催化剂®技术

pictograms

Flame
GHS02

signalword

Warning

hcodes

H228

Hazard Classifications

Flam. Sol. 2

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ6941
MKCZ5993
MKCV6640
MKCT0979
MKCS7342

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Ryan P Murelli et al.
Organic letters, 9(9), 1749-1752 (2007-04-03)
[reaction: see text] In the presence of ruthenium-based olefin metathesis catalysts and triphenylphosphine, alpha,beta-unsaturated aldehydes can be olefinated with diazoacetates. This ruthenium-catalyzed transformation has been employed in tandem with olefin cross-metathesis to convert terminal olefins into 1,3-dienoic esters in a
A K Chatterjee et al.
Organic letters, 1(11), 1751-1753 (2000-06-03)
[formula: see text] Trisubstituted alkenes have been prepared for the first time via intermolecular olefin cross-metathesis, using 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium alkylidene complexes 3a,b in good yields with moderate E selectivity. In addition, protected alcohols near the geminal disubstituted olefin improve reactivity
Kevin M Kuhn et al.
Organic letters, 12(5), 984-987 (2010-02-10)
A series of ruthenium catalysts have been screened under ring-closing metathesis (RCM) conditions to produce five-, six-, and seven-membered carbamate-protected cyclic amines. Many of these catalysts demonstrated excellent RCM activity and yields with as low as 500 ppm catalyst loadings.
T M Trnka et al.
Accounts of chemical research, 34(1), 18-29 (2001-02-15)
In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advances in catalyst design. State-of-the-art ruthenium catalysts are not only highly active but also
Schrodi, Y.; Pederson, R.L.
Aldrichimica Acta, 40, 45-45 (2007)
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相关内容

Grubbs Group – Prof. Product Portal

Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.

Olefin Metathesis Application Guide

The Olefin Application Metathesis Application Guide provides - The Key Features of Metathesis, General Reaction Procedures, Guidance for Choosing the Correct Metathesis Route, A Metathesis Quick Guide

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