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表单
solid
mp
104.1-109.2 °C
官能团
amine
phosphine
SMILES字符串
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
InChI
1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
InChI key
ZIAZHUWEJYUGEO-FBHGDYMESA-N
应用
Methyl-BoPhoz can be used:
- As an efficient ligand for asymmetric hydrogenation reactions.
- To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.
- To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.
法律信息
与 Johnson Matthey Catalyst 联合销售,仅供研究使用。适用美国专利 US6590115 以及由此产生的任何专利。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Protecting-group-free synthesis of a dual CCK1/CCK2 receptor antagonist
Liu J, et al.
Organic & Biomolecular Chemistry, 9(8), 2654-2660 (2011)
Enantioselective Access to Chiral Drugs by using Asymmetric Hydrogenation Catalyzed by Rh (P-OP) Complexes
Etayo P, et al.
Chemistry?A European Journal , 17(50), 13978-13982 (2011)
The preparation of enantiomerically pure cyclopropylalanine.
Boaz NW, et al.
Tetrahedron Asymmetry, 14(22), 3575-3580 (2003)
商品
P-Phos ligand family enhances catalysis, featuring atropisomeric biaryl bisphosphine with unique structural elements.
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