旋光性
[α]20/D −35 to ±5°, c = 1
质量水平
浓度
1 M in pentane
bp
35-36 °C
密度
0.638 g/mL at 25 °C
储存温度
−20°C
SMILES字符串
C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C
InChI
1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1
InChI key
ZIXZBDJFGUIKJS-RLEROFIGSA-N
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应用
方便、无盐且稳定的手性烯丙基硼烷溶液,用于醛的不对称烯丙基化反应,生成手性高烯丙醇。
其他说明
本品冷却储藏时可能会变浑浊,不影响使用
Under refrigerator storage, these salt-free, Ipc2B(allyl) reagents do not show any appreciable decrease in selectivity is observed after several months. They exhibit excellent reactivity and reactions can be performed at 5°C, even in water.
警示用语:
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
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Tetrahedron Letters, 54.36, 4830-4833 (2013)
Stereoselective Synthesis of 2, 6?Disubstituted Piperidines Using the Iridium?Catalyzed Allylic Cyclization as Configurational Switch: Asymmetric Total Synthesis of (+)?241 D and Related Piperidine Alkaloids.
European Journal of Chemistry, 15.9, 2050-2054 (2009)
Aldrichimica Acta, 25, 23-23 (2002)
Total synthesis of hypermodified epothilone analogs with potent in vitro antitumor activity
Organic Letters, 10.6, 1183-1186 (2008)
Total synthesis of cryptomoscatone F1 through an asymmetric aldol approach
Tetrahedron Asymmetry, 26.21, 1251-1255 (2015)
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