检测方案
96%
形式
solid
旋光性
[α]22/D +52±5°, c = 1 in chloroform
折射率
n20/D 1.5509
密度
1.0459 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
C[Si](C)(C)OC([C@H]1CCCN1)(c2ccccc2)c3ccccc3
InChI
1S/C20H27NOSi/c1-23(2,3)22-20(19-15-10-16-21-19,17-11-6-4-7-12-17)18-13-8-5-9-14-18/h4-9,11-14,19,21H,10,15-16H2,1-3H3/t19-/m1/s1
InChI key
RSUHWMSTWSSNOW-LJQANCHMSA-N
一般描述
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether is a diarylprolinol silyl ether organocatalyst.
应用
(R)-(+)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether can be used as a catalyst to synthesize:
- Glycofused tricyclic derivatives, which are used in the development of amyloid β-peptide diagnostic tools.
- Cyclohexene carbaldehyde derivatives by reacting benzoylnitromethane with aliphatic enals.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and Preliminary Biological Evaluation of Fluorescent Glycofused Tricyclic Derivatives of Amyloid β-Peptide Ligands
D'Orazio G, et al.
European Journal of Organic Chemistry, 2016(9), 1660-1664 (2016)
Organocatalytic Cascade Reaction of Aliphatic Enals and Benzoylnitromethane: Synthesis of Enantioenriched Tetrasubstituted Cyclohexene Carbaldehyde
David Rodriguez FA, et al.
Journal of Chemistry, 2020 (2020)
The diarylprolinol silyl ether system: a general organocatalyst.
Jensen KL, et al.
Accounts of Chemical Research, 45(2), 248-264 (2011)
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