所有图片(2)
About This Item
经验公式（希尔记法）:
C13H30BF4P
CAS号:
分子量:
304.16
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
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方案
95%
表单
solid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
mp
258-262 °C
官能团
phosphine
SMILES字符串
F[B-](F)(F)F.CC(C)(C)C[PH+](C(C)(C)C)C(C)(C)C
InChI
1S/C13H29P.BF4/c1-11(2,3)10-14(12(4,5)6)13(7,8)9;2-1(3,4)5/h10H2,1-9H3;/q;-1/p+1
InChI key
UWNPUGYQGIWNRI-UHFFFAOYSA-O
应用
在溴代芳烃和氯代芳烃的钯催化胺基化反应中，该新戊基膦配体比三叔丁基膦更出色。
- Cocatalyst for palladium-catalyzed Kumada couplings
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Lensey L Hill et al.
The Journal of organic chemistry, 71(14), 5117-5125 (2006-07-01)
Di(tert-butyl)neopentylphosphine (DTBNpP) in combination with palladium sources provided catalysts with comparable or better activity for the Hartwig-Buchwald amination of aryl bromides than tri(tert-butyl)phosphine (TTBP) under mild conditions. DTBNpP also provided effective catalysts for amination reactions of aryl chlorides at elevated
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