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方案
95%
折射率
n20/D 1.5107
密度
1.1223 g/mL at 25 °C
储存温度
−20°C
SMILES字符串
CCCC[Sn](CCCC)(CCCC)c1cccn1C
InChI
1S/C5H6N.3C4H9.Sn/c1-6-4-2-3-5-6;3*1-3-4-2;/h2-4H,1H3;3*1,3-4H2,2H3;
InChI key
DINAKCGOEKXDTP-UHFFFAOYSA-N
应用
1-Methyl-2-(tributylstannyl)pyrrole can be used as a reactant to prepare:
- Bithienylpyrrole derivatives through a Stille coupling reaction with bithienyl bromides in the presence of Pd catalyst.
- Di(bisthienyl)-o-carborane (DBTC) by reacting with 5,5′-dibromo-o-carboranyl-bisthiophenes using Pd catalyst. DBTC is electropolymerized to produce conducting polymers.
- Poly(Py-BTz-Py) (2-butyl-4,7-bis(1-methyl-1H-pyrrol-2-yl)-2H-benzo[d][1,2,3]triazole) via Stille coupling reaction. Poly(Py-BTz-Py) can be used as an organic photocatalyst for the formation C-C bond under visible light irradiation.
警示用语:
Danger
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
208.9 °F - closed cup
闪点(°C)
98.3 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
新产品
Molecular Design of Donor-Acceptor-Type Organic Photocatalysts for Metal-free Aromatic C- C Bond Formations under Visible Light
advanced synthesis and catalysis, 360(22), 4312- 4318 (2018)
Molecular Design of Donor-Acceptor-Type Organic Photocatalysts for Metal-free Aromatic C- C Bond Formations under Visible Light
Advanced Synthesis & Catalysis, 360(22), 4312- 4318 (2018)
Synthesis of π-conjugated systems bearing thiophene and pyrrole heterocycles through palladium catalyzed cross-coupling reactions
Tetrahedron, 72(15), 1881-1887 (2016)
Synthesis and electropolymerization of a series of 2, 2?-(ortho-carboranyl) bisthiophenes
Journal of Organometallic Chemistry, 828(15), 157- 165 (2017)
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