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Merck
CN

675679

Sigma-Aldrich

1-甲基-2-(三丁基锡基)吡咯

95%

别名:

(1-甲基吡咯-2-基)三丁基锡, 2-(三丁基锡基)-1-甲基吡咯, N-甲基-2-(三丁基锡基)吡咯

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About This Item

线性分子式:
[H3C(C4H3N)]Sn[(CH2)3CH3]3
分子量:
370.16
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

方案

95%

折射率

n20/D 1.5107

密度

1.1223 g/mL at 25 °C

储存温度

−20°C

SMILES字符串

CCCC[Sn](CCCC)(CCCC)c1cccn1C

InChI

1S/C5H6N.3C4H9.Sn/c1-6-4-2-3-5-6;3*1-3-4-2;/h2-4H,1H3;3*1,3-4H2,2H3;

InChI key

DINAKCGOEKXDTP-UHFFFAOYSA-N

应用

1-Methyl-2-(tributylstannyl)pyrrole can be used as a reactant to prepare:
  • Bithienylpyrrole derivatives through a Stille coupling reaction with bithienyl bromides in the presence of Pd catalyst.
  • Di(bisthienyl)-o-carborane (DBTC) by reacting with 5,5′-dibromo-o-carboranyl-bisthiophenes using Pd catalyst. DBTC is electropolymerized to produce conducting polymers.
  • Poly(Py-BTz-Py) (2-butyl-4,7-bis(1-methyl-1H-pyrrol-2-yl)-2H-benzo[d][1,2,3]triazole) via Stille coupling reaction. Poly(Py-BTz-Py) can be used as an organic photocatalyst for the formation C-C bond under visible light irradiation.

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

208.9 °F - closed cup

闪点(°C)

98.3 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number

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访问文档库

Molecular Design of Donor-Acceptor-Type Organic Photocatalysts for Metal-free Aromatic C- C Bond Formations under Visible Light
Wang L, et al.
advanced synthesis and catalysis, 360(22), 4312- 4318 (2018)
Molecular Design of Donor-Acceptor-Type Organic Photocatalysts for Metal-free Aromatic C- C Bond Formations under Visible Light
Wang L, et al.
Advanced Synthesis & Catalysis, 360(22), 4312- 4318 (2018)
Synthesis of π-conjugated systems bearing thiophene and pyrrole heterocycles through palladium catalyzed cross-coupling reactions
Castro MCR and Raposo MMM
Tetrahedron, 72(15), 1881-1887 (2016)
Synthesis and electropolymerization of a series of 2, 2?-(ortho-carboranyl) bisthiophenes
Zhao N, et al.
Journal of Organometallic Chemistry, 828(15), 157- 165 (2017)

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