推荐产品
方案
96%
折射率
n20/D 1.4488
密度
0.9158 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
CC(O[Si](C)(C)C(C)(C)C)C#CB1OC(C)(C)C(C)(C)O1
InChI
1S/C16H31BO3Si/c1-13(18-21(9,10)14(2,3)4)11-12-17-19-15(5,6)16(7,8)20-17/h13H,1-10H3
InChI key
KGDJKWYVGUGRCG-UHFFFAOYSA-N
应用
炔基硼酸酯可参与一系列区域选择性和立体选择性碳-碳键形成
过程，包括烯炔的交叉复分解反应和 Alder 烯反应。
过程，包括烯炔的交叉复分解反应和 Alder 烯反应。
储存分类代码
12 - Non Combustible Liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
Mansuk Kim et al.
Organic letters, 7(9), 1865-1868 (2005-04-23)
[reaction: see text] Regio- and stereoselective enyne cross metathesis reactions between borylated alkynes and terminal alkenes were realized to provide a variety of functionalized vinyl boronates. High chemical yield and regioselectivity was achieved irrespective of substituents on the alkyne and
Eric C Hansen et al.
Journal of the American Chemical Society, 127(10), 3252-3253 (2005-03-10)
Ruthenium-catalyzed Alder ene reactions between borylated alkynes and terminal alkenes give the corresponding beta,beta-disubstituted vinyl boronates with high selectivity for the branched isomer. The stereochemistry of the vinyl boronate moiety was the result of a formal trans addition of the
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