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Merck
CN
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文件

安全信息

674613

Sigma-Aldrich

四(二甲氨基)乙烯

别名:

TDAE, 四(乙氨基)乙烯

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About This Item

线性分子式:
[(CH3)2N]2C=C[N(CH3)2]2
CAS号:
996-70-3
分子量:
200.32
Beilstein:
1705900
EC 号:
213-638-1
MDL编号:
MFCD00009601
UNSPSC代码:
12352116
PubChem化学物质编号:
24885226
NACRES:
NA.22

质量水平

100

反应适用性

reaction type: C-C Bond Formation

折射率

n20/D 1.48 (lit.)

bp

59 °C/0.9 mmHg (lit.)

密度

0.861 g/mL at 25 °C (lit.)

SMILES字符串

CN(C)\C(N(C)C)=C(\N(C)C)N(C)C

InChI

1S/C10H24N4/c1-11(2)9(12(3)4)10(13(5)6)14(7)8/h1-8H3

InChI key

CBXRMKZFYQISIV-UHFFFAOYSA-N

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相关类别

应用

参与TDAE催化的偶联反应和分子内Buchwald反应

作为还原剂

作为以下过程的反应物：
  • 双氧合反应
  • 将铝阴离子插入C-N键
  • 与氧气的化学发光反应
用于将 α-溴代酮类化合物转化成 1,4-二酮类化合物。

象形图

FlameCorrosion
GHS02,GHS05

警示用语：

Danger

危险声明

H226,H314

危险分类

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Patrick Weis et al.
Physical chemistry chemical physics : PCCP, 21(35), 18877-18892 (2019-08-23)
We present high-resolution trapped ion mobility spectrometry (TIMS) measurements for fullerene ions in molecular nitrogen. Three different charge states were studied (monocations, monoanions and dianions) with fullerenes ranging in size from C60 to C150. Ions were prepared by either electrospray
Tetrahedron Letters, 47, 5565-5565 (2006)
Kyungwho Choi et al.
ACS applied materials & interfaces, 10(28), 23891-23899 (2018-06-28)
Thermoelectric (TE) energy conversion with nontraditional organic materials is promising in wearable electronics and roll-to-roll manufacturing because of mechanical flexibility, lightweight, and easy processing. Although typical organic materials have a benefit of low thermal conductivity that creates a large temperature
Wen-Bin Luo et al.
Advanced materials (Deerfield Beach, Fla.), 27(43), 6862-6869 (2015-09-25)
Porous AgPd-Pd composite nanotubes (NTs) are used as an efficient bifunctional catalyst for the oxygen reduction and evolution reactions in lithium-oxygen batteries. The porous NT structure can facilitate rapid O2 and electrolyte diffusion through the NTs and provide abundant catalytic
Otmar Geiss et al.
Journal of chromatography. A, 1566, 13-22 (2018-06-28)
Polycyclic Aromatic Hydrocarbons (PAHs) have been detected in rubber and plastic components of a number of consumer products such as toys, tools for domestic use, sports equipment, and footwear, with carbon black and extender oils having been identified as principal
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商品

Tetrakis(dimethylamino)ethylene (TDAE)

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

四（二甲基氨基）乙烯（TDAE）

在2001年，佛罗里达大学的William Dolbier，Jr.教授报告了一种亲核三氟甲基化的方法，该方法基于在强力双电子还原剂四（二甲基氨基）乙烯（TDAE）存在下使用CF3I生成三氟甲基阴离子。

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