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Merck
CN
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文件

安全信息

674583

Sigma-Aldrich

高氯酸银

anhydrous, 97%

别名:

Perchloric acid silver(1+) salt, Silver(1+) perchlorate

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About This Item

线性分子式:
AgClO4
CAS号:
7783-93-9
分子量:
207.32
EC 号:
232-035-4
MDL编号:
MFCD00003400
UNSPSC代码:
12352302
PubChem化学物质编号:
24885223
NACRES:
NA.23

等级

anhydrous

质量水平

100

检测方案

97%

形式

solid

反应适用性

reagent type: catalyst
core: silver

杂质

≤0.1% Insoluble matter

mp

486 °C (lit.)

溶解性

benzene: slightly soluble(lit.)
pyridine: slightly soluble(lit.)

密度

2.8 g/mL at 25 °C (lit.)

SMILES字符串

[Ag+].[O-]Cl(=O)(=O)=O

InChI

1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1

InChI key

YDHABVNRCBNRNZ-UHFFFAOYSA-M

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相关类别

应用

  • Anion exchange dynamics in the capture of perchlorate by a cationic Ag-based MOF：研究银基金属有机骨架捕获高氯酸盐的阴离子交换动力学和结构转换(Colinas et al., 2017)。

象形图

Flame over circleCorrosion
GHS03,GHS05

警示用语：

Danger

危险声明

H272,H314

危险分类

Ox. Sol. 2 - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

分析证书(COA)

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Masafumi Harada et al.
Journal of colloid and interface science, 339(2), 373-381 (2009-09-08)
Metal particles of silver (Ag) were synthesized by the photoreduction of silver perchlorate (AgClO(4)) in water-in-ionic liquid (ILs) microemulsions consisting of Tween 20, water and ionic liquids. The ILs were tetrafluoroborate anions associated with the cations 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF(4)]) and
E Petráková et al.
Carbohydrate research, 233, 101-112 (1992-09-02)
Specifically deoxygenated methyl alpha-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected alpha-isomaltosyl chloride with suitably blocked derivatives of methyl alpha-D-glucopyranoside deoxygenated respectively at positions 2, 3, and 4, followed by deprotection.
Ken Sakai et al.
Acta crystallographica. Section B, Structural science, 60(Pt 3), 255-262 (2004-05-19)
The third crystal structure containing the hydroxo-bridged cis-diammineplatinum(II) dimer has been determined for a perchlorate salt of the complex, [Pt(2)(NH(3))(4)(micro-OH)(2)](ClO(4))(2). However, the dinuclear cations in the nitrate and the carbonate salts, [Pt(2)(NH(3))(4)(micro-OH)(2)](NO(3))(2) [Faggiani, Lippert, Lock & Rosenberg (1977). J. Am.
Glycosylation via Cp2ZrCl2/AgClO4-mediated activation of anomeric sulfoxides.
P Wipf et al.
The Journal of organic chemistry, 66(23), 7910-7914 (2001-11-10)
C Rentel et al.
Analytical chemistry, 70(20), 4394-4400 (1998-10-31)
In LC/MS, nonpolar substances in the majority of cases cannot be ionized by standard electrospray ionization (ESI) because they obviously lack a site for protonation or deprotonation. The ionization of carotenoids and tocopherols can be greatly enhanced by the addition
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