形式
solid
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
SMILES字符串
[Pd].O[Al]=O
InChI
1S/Al.H2O.O.Pd/h;1H2;;/q+1;;;/p-1
InChI key
BBEPUHUDSUQPRM-UHFFFAOYSA-M
一般描述
非均相强效钯催化剂。
应用
Catalyst for:
- Solvent-free hydrogenation
- Aerobic alcohol oxidation
可回收纳米催化剂，用于伯胺的外消旋作用。与脂肪酶共同使用，通过动态动力学拆分生成对映纯胺。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Min Serk Kwon et al.
Organic letters, 7(6), 1077-1079 (2005-03-12)
[reaction: see text] A new aluminum hydroxide-supported palladium catalyst (1) made by a one-pot synthesis through nanoparticle generation and gelation shows a dual catalytic activity for olefinic hydrogenation and aerobic alcohol oxidation.
Mahn-Joo Kim et al.
Organic letters, 9(6), 1157-1159 (2007-02-13)
A practical procedure for the dynamic kinetic resolution (DKR) of primary amines has been developed. This procedure employs a palladium nanocatalyst as the racemization catalyst, a commercial lipase (Novozym-435) as the resolution catalyst, and ethyl acetate or ethyl methoxyacetate as
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