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About This Item
线性分子式:
[(C10H15)Ru(P((C6H5)3))2Cl]
CAS号:
分子量:
796.32
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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表单
solid
质量水平
反应适用性
core: ruthenium
reagent type: catalyst
reaction type: click chemistry
mp
128 °C (D)
储存温度
2-8°C
SMILES字符串
Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
InChI
1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1
InChI key
KLXKSZDVKAWYRT-UHFFFAOYSA-M
应用
叠氮化物与乙炔环加成反应的催化剂，专一性生成 1,5-二取代三唑，相比之下，常见的铜催化则具有 1,4-区域选择性。钌催化还使得可在此类"点击环加成反应"中使用内炔。
活性自由基聚合反应的多功能催化剂
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Metal-catalyzed living radical polymerization.
M Kamigaito et al.
Chemical reviews, 101(12), 3689-3746 (2001-12-13)
Li Zhang et al.
Journal of the American Chemical Society, 127(46), 15998-15999 (2005-11-17)
Cp*RuCl(PPh3)2 is an effective catalyst for the regioselective "fusion" of organic azides and terminal alkynes, producing 1,5-disubstituted 1,2,3-triazoles. Internal alkynes also participate in this catalysis, resulting in fully substituted 1,2,3-triazoles.
商品
Click chemistry is an approach to the synthesis of drug-like molecules that can accelerate the drug discovery process by using a few practical and reliable reactions.
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