所有图片(1)
About This Item
经验公式（希尔记法）:
C11H22N2O2
CAS号:
分子量:
214.30
Beilstein:
7023564
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
≥96.5%
97%
表单
solid
旋光性
[α]/D -26±2°, c = 1 in chloroform
光学纯度
ee: ≥99.0%
官能团
amine
SMILES字符串
CC(C)(C)OC(=O)N[C@@H]1CCCC[C@H]1N
InChI
1S/C11H22N2O2/c1-11(2,3)15-10(14)13-9-7-5-4-6-8(9)12/h8-9H,4-7,12H2,1-3H3,(H,13,14)/t8-,9-/m1/s1
InChI key
AKVIZYGPJIWKOS-RKDXNWHRSA-N
应用
(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:
- An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
- A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
Robust and Recyclable Self-Supported Chiral Nickel Catalyst for the Enantioselective Michael Addition
Bissessar D, et al.
advanced synthesis and catalysis, 358(12), 1982-1988 (2016)
Enantioselective Desymmetrization of Prochiral Cyclohexanones by Organocatalytic Intramolecular Michael Additions to α,β-Unsaturated Esters
Gammack Y, et al.
Angewandte Chemie (International Edition in English), 54(16), 4899-4903 (2015)
Robust and Recyclable Self-Supported Chiral Nickel Catalyst for the Enantioselective Michael Addition
Bissessar D, et al.
Advanced Synthesis & Catalysis, 358(12), 1982-1988 (2016)
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