所有图片(1)
About This Item
经验公式（希尔记法）:
C18Cl12O6P · C16H36N
CAS号:
分子量:
1011.06
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
![(11bR)-(–)-4,4-二丁基-4,5-二氢-2,6-双(3,4,5-三氟苯基)-3H-二萘[2,1-c:1′,2′-e]氮杂卓溴化物 Nagase purity](/deepweb/assets/sigmaaldrich/product/structures/147/005/c2a47bf2-5270-4469-9f3e-138f76f8f4c3/640/c2a47bf2-5270-4469-9f3e-138f76f8f4c3.png)
![(R)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-联萘-2,2′-二基磷酸氢酯 95%](/deepweb/assets/sigmaaldrich/product/structures/270/636/14dc9413-bcb4-478c-8e4d-3605317c13a5/640/14dc9413-bcb4-478c-8e4d-3605317c13a5.png)
质量水平
方案
≥98.5% (31P-NMR)
表单
solid
旋光性
[α]/D -370±10°, c = 0.1 in ethanol
官能团
amine
chloro
储存温度
2-8°C
SMILES字符串
CCCC[N+](CCCC)(CCCC)CCCC.Clc1c(Cl)c(Cl)c2O[P-]345(Oc2c1Cl)Oc6c(Cl)c(Cl)c(Cl)c(Cl)c6O3.Clc7c(Cl)c(Cl)c(O4)c(O5)c7Cl
InChI
1S/C18Cl12O6P.C16H36N/c19-1-2(20)8(26)14-13(7(1)25)31-37(32-14,33-15-9(27)3(21)4(22)10(28)16(15)34-37)35-17-11(29)5(23)6(24)12(30)18(17)36-37;1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4/h;5-16H2,1-4H3/q-1;+1
InChI key
GCGVBYHPNKLLAV-UHFFFAOYSA-N
一般描述
Δ-TRISPHAT四丁基铵盐，含有一个六配位的磷阴离子，是一种手性NMR溶剂和不对称诱导剂。
应用
手性阴离子介导的不对称化学
包装
无底玻璃瓶。内含物在插入的融合锥体内。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
C3-Symmetric Trinuclear Molybdenum Cluster Sulfides: Configurational Stability, Supramolecular Stereocontrol, and Absolute Configuration Assignment.
Frantz R, et al.
Inorganic Chemistry, 46(25), 10717-10723 (2007)
Application of TRISPHAT anion as NMR chiral shift reagent.
Lacour Je, et al.
Chemical Communications (Cambridge, England), 23, 2285-2286 (1997)
Bimacrocyclic concave N-heterocyclic carbenes (NHCs): Synthesis, structure and application in catalyses.
Winkelmann O and Luning U.
Supramolecular Chemistry, 21(3-4), 223-229 (2009)
Chiral ion mediated asym. chemistry
Lacour, J.
Chimia, 56, 672-675 (2002)
Jerome Lacour et al.
Organic & biomolecular chemistry, 3(1), 15-19 (2004-12-17)
Chemical reactions and processes often involve chiral, yet racemic, cationic reagents, intermediates or products. To afford instead non racemic or enantiopure compounds, an asymmetric ion pairing of the cations with enantiopure anions can be considered--the counter ions behaving as asymmetric
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门