所有图片(1)
About This Item
经验公式（希尔记法）:
C18H36P2
CAS号:
分子量:
314.43
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
折射率
n20/D 1.5249
沸点
104-106 °C/0.05 mmHg
密度
0.939 g/mL at 25 °C
官能团
phosphine
SMILES字符串
CC[C@@H]1CC[C@@H](CC)P1CCP2[C@H](CC)CC[C@H]2CC
InChI
1S/C18H36P2/c1-5-15-9-10-16(6-2)19(15)13-14-20-17(7-3)11-12-18(20)8-4/h15-18H,5-14H2,1-4H3/t15-,16-,17-,18-/m1/s1
InChI key
QOLRLVPABLMMKI-BRSBDYLESA-N
应用
(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane can be used as a reactant to prepare:
It can also be used as a catalyst in the enantioselective preparation of (perfluoroalkyl)butenyldiketones via cross Rauhut-Currier reaction of β-perfluoroalkylenones and vinyl ketones.
- Chromium diphosphine chloride complex which is employed as a catalyst for chemoselective oligomerization reaction.
- α-Arylpyrrolidines by Suzuki-Miyaura cross-coupling and enantioselective copper-catalyzed intramolecular hydroamination reactions.
It can also be used as a catalyst in the enantioselective preparation of (perfluoroalkyl)butenyldiketones via cross Rauhut-Currier reaction of β-perfluoroalkylenones and vinyl ketones.
法律信息
与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Phosphine-Catalyzed Asymmetric Intermolecular Cross Rauhut-Currier Reaction of β-Perfluoroalkyl-Substituted Enones and Vinyl Ketones
T Mengna, et al.
advanced synthesis and catalysis, 359(19), 3347-3353 (2017)
Phospholane-Based Ligands for Chromium-Catalyzed Ethylene Tri-and Tetramerization
Boelter SD, et al.
Organometallics, 39(7), 976-987 (2020)
Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles
Dai X-J, et al.
Angewandte Chemie (International Edition in English), 131(11), 3445-3449 (2019)
Phosphine-Catalyzed Asymmetric Intermolecular Cross Rauhut-Currier Reaction of β-Perfluoroalkyl-Substituted Enones and Vinyl Ketones
T Mengna, et al.
Advanced Synthesis & Catalysis, 359(19), 3347-3353 (2017)
商品
Asymmetric hydrogenation enables scalable synthesis of single-enantiomer compounds with minimal byproducts, ideal for commercial manufacturing.
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