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浓度
0.5 M in anhydrous tetrahydrofuran
杂质
≤50 ppm water
密度
0.913 g/mL at 25 °C
SMILES字符串
[Li+].[Cl-]
InChI
1S/ClH.Li/h1H;/q;+1/p-1
InChI key
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
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应用
氯化锂(LiCl)是亲核氯化物阴离子的来源,它可以将醇转化为氯代烷。它催化二异丙基氨基锂(LDA)介导的一系列芳烃的邻位化。LiCl 溶液也用于制备有机卤化锌。
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-4.0 °F - closed cup
闪点(°C)
-20 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
On-demand synthesis of organozinc halides under continuous flow conditions.
Nature Protocols, 13(1), 324-324 (2018)
Lithium Chloride.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
The Journal of organic chemistry, 74(5), 2231-2233 (2009-02-05)
Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 degrees C reveal substantial accelerations by as little as 0.5 mol % of LiCl (relative to LDA). Substrate dependencies suggest a specific range of reactivity
PloS one, 7(12), e51746-e51746 (2012-12-29)
Lineage allocation of the marrow mesenchymal stem cells (MSCs) to osteoblasts and adipocytes is dependent on both Wnt signaling and PPARγ2 activity. Activation of PPARγ2, an essential regulator of energy metabolism and insulin sensitivity, stimulates adipocyte and suppresses osteoblast differentiation
Proceedings of the National Academy of Sciences of the United States of America, 110(36), 14765-14770 (2013-08-22)
Diphtheria toxin-mediated, acute ablation of hypothalamic neurons expressing agouti-related protein (AgRP) in adult mice leads to anorexia and starvation within 7 d that is caused by hyperactivity of neurons within the parabrachial nucleus (PBN). Because NMDA glutamate receptors are involved
商品
PEPPSI™ palladium N-heterocyclic-carbene catalyst system enhances efficiency and functional group tolerance in catalysis.
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