浓度
0.5 M in anhydrous tetrahydrofuran
杂质
≤50 ppm water
密度
0.913 g/mL at 25 °C
SMILES字符串
[Li+].[Cl-]
InChI
1S/ClH.Li/h1H;/q;+1/p-1
InChI key
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
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应用
氯化锂(LiCl)是亲核氯化物阴离子的来源,它可以将醇转化为氯代烷。它催化二异丙基氨基锂(LDA)介导的一系列芳烃的邻位化。LiCl 溶液也用于制备有机卤化锌。
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
WGK
WGK 1
闪点(°F)
-4.0 °F
闪点(°C)
-20 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Lithium Chloride.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
On-demand synthesis of organozinc halides under continuous flow conditions.
Nature Protocols, 13(1), 324-324 (2018)
The Journal of biological chemistry, 289(16), 11007-11019 (2014-03-13)
Amyloid precursor protein (APP) undergoes post-translational modification, including O- and N-glycosylation, ubiquitination, and phosphorylation as it traffics through the secretory pathway. We have previously reported that copper promotes a change in the cellular localization of APP. We now report that
Proceedings of the National Academy of Sciences of the United States of America, 111(40), 14325-14331 (2014-09-17)
Human telomeric DNA consists of tandem repeats of the sequence 5'-TTAGGG-3' that can fold into various G-quadruplexes, including the hybrid, basket, and propeller folds. In this report, we demonstrate use of the α-hemolysin ion channel to analyze these subtle topological
The Journal of organic chemistry, 74(5), 2231-2233 (2009-02-05)
Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 degrees C reveal substantial accelerations by as little as 0.5 mol % of LiCl (relative to LDA). Substrate dependencies suggest a specific range of reactivity
商品
PEPPSI™ palladium N-heterocyclic-carbene catalyst system enhances efficiency and functional group tolerance in catalysis.
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