667234
氯(五甲基环戊二烯基)(环辛二烯)钌(II)
别名:
Cp*RuCl(cod), (1,5-环辛二烯)(η5-五甲基环戊二烯)氯化钌, (1,5-环辛二烯)(五甲基环戊二烯)氯化钌, 1,5-环辛二烯，钌复合物
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关于此项目
经验公式（希尔记法）:
C18H27ClRu
化学文摘社编号:
分子量:
379.93
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
SMILES string
Cl[Ru].C1CC=CCCC=C1.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI key
MQMQNIQJGNBEMG-ONEVTFJLSA-M
mp
143-147 °C
storage temp.
−20°C
reaction suitability
reagent type: catalyst
core: ruthenium
reaction type: click chemistry
Quality Level
Application
(1,5-环辛二烯)(五甲基环戊二烯)氯化钌是用于形成碳-碳和碳-杂原子键的均相催化剂。
它可用于：
它可用于：
- 催化炔基硼酸酯、炔丙醇和末端炔烃的环化三聚反应(cyclotrimerization)以形成芳基硼酸酯，芳基硼酸酯可进行钯（II）催化的羰基化反应以形成高度取代的苯酞。
- 催化降冰片烯和降冰片二烯与炔烃的C-C偶联以形成[2 + 2]环加成产物。
- 与2-二苯基膦基乙胺-叔丁醇钾结合形成一种可催化手性非外消旋仲醇快速消旋的三元催化剂体系。
- 合成具有磷基配体（如双膦胺）的新有机钌配合物
- 催化有机二硫化物和烯烃的加成反应生成二甲基二硫醚（vic-dithioether）。
signalword
Danger
hcodes
pcodes
Hazard Classifications
Water-react 2
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
此项目有
Rapid racemization of chiral non-racemic sec-alcohols catalyzed by (η5-C5(CH3)5)Ru complexes bearing tertiary phosphine-primary amine chelate ligands
Ito M, et al.
Tetrahedron Letters, 44(40), 7521-7523 (2003)
Ruthenium (II) chemistry of phosphorus-based ligands, Ph2PN(R)PPh2 (R= Me or Ph) and Ph2PN(Ph)P(E)Ph2 (E= S or Se). Solution thermochemical study of ligand substitution reactions in the Cp′ RuCl (COD)(Cp′= Cp, Cp*; COD= cyclooctadiene) system
Balakrishna MS, et al.
Journal of Organometallic Chemistry, 599(2), 159-165 (2000)
First Transition-Metal Complex Catalyzed Addition of Organic Disulfides to Alkenes Enables the Rapid Synthesis of v icinal-Dithioethers
Kondo T, et al.
Journal of the American Chemical Society, 121(2), 482-483 (1999)
[2+ 2] Cycloaddition of norbornenes with alkynes catalyzed by ruthenium complexes
Mitsudo T-A, et al.
Angewandte Chemie (International ed. in English), 33(5), 580-581 (1994)
Cp*RuCl-catalyzed formal intermolecular cyclotrimerization of three unsymmetrical alkynes through a boron temporary tether: Regioselective four-component coupling synthesis of phthalides
Yamamoto Y, et al.
Journal of the American Chemical Society, 127(26), 9625-9631 (2005)
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