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About This Item
经验公式（希尔记法）:
C14H18BClO2
CAS号:
分子量:
264.56
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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方案
97%
折射率
n20/D 1.536
沸点
138-140 °C/0.9-1.0 mmHg
密度
1.049 g/mL at 25 °C
SMILES字符串
CC1(C)OB(OC1(C)C)\C=C\c2cccc(Cl)c2
InChI
1S/C14H18BClO2/c1-13(2)14(3,4)18-15(17-13)9-8-11-6-5-7-12(16)10-11/h5-10H,1-4H3/b9-8+
InChI key
NZBKTAJNGYXYSQ-CMDGGOBGSA-N
应用
trans-2-(3-Chlorophenyl)vinylboronic acid pinacol ester can be used as a reactant:
- To prepare aryl derivatives by C−C bond formation via palladium-catalyzed Suzuki−Miyaura reaction.
- In the diastereoselective synthesis of alkenes via K3PO4-promoted transition metal-free nucleophilic substitution of unactivated alkyl triflates.
- To synthesize (3-chlorophenyl)cyclopropyl boronic acid pinacol ester by reacting with diazomethane.
储存分类代码
12 - Non Combustible Liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
法规信息
新产品
Mild Base Promoted Nucleophilic Substitution of Unactivated sp3-Carbon Electrophiles with Alkenylboronic Acids
Liu Shiwen, et al.
advanced synthesis and catalysis, 360(19), 3667-3671 (2018)
Automated library synthesis of cyclopropyl boronic esters employing diazomethane in a tube-in-tube flow reactor
Koolman HF, et al.
Organic & Biomolecular Chemistry, 14(27), 6591-6595 (2016)
Mild Base Promoted Nucleophilic Substitution of Unactivated sp3-Carbon Electrophiles with Alkenylboronic Acids
Liu Shiwen, et al.
Advanced Synthesis & Catalysis, 360(19), 3667-3671 (2018)
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