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质量水平
方案
96%
表单
solid
mp
218-221 °C
官能团
amine
ether
ketal
phenyl
SMILES字符串
CN(C)P1OC([C@@H]2OC(C)(C)O[C@H]2C(O1)(c3ccccc3)c4ccccc4)(c5ccccc5)c6ccccc6
InChI
1S/C33H34NO4P/c1-31(2)35-29-30(36-31)33(27-21-13-7-14-22-27,28-23-15-8-16-24-28)38-39(34(3)4)37-32(29,25-17-9-5-10-18-25)26-19-11-6-12-20-26/h5-24,29-30H,1-4H3/t29-,30-/m1/s1
InChI key
DRPNADVMTMEWQY-LOYHVIPDSA-N
应用
亚磷酰胺配体,用于丙烯基硼酸酯的铱催化不对称烯丙基化反应。还用于二乙基锌的铜催化不对称共轭加成至氨基酸衍生的 α,β-不饱和亚胺。
法律信息
经 DSM 授权销售,仅供研究之用。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Tetrahedron Letters, 48, 3305-3305 (2007)
Organic letters, 8(23), 5405-5408 (2006-11-03)
[Structure: see text] A highly enantioselective synthesis of alpha-dehydroaminoacids with a stereogenic center in the gamma position through copper-catalyzed asymmetric conjugate addition of diethylzinc to alpha,beta-unsaturated imines using a TADDOL-derived phosphoramidite complex is reported.
商品
DSM collaboration offers MonoPhos™ ligands for research, based on the BINOL platform by Feringa and co-workers.
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