所有图片(1)
About This Item
经验公式（希尔记法）:
C9H21GdO3
CAS号:
分子量:
334.51
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
方案
99%
表单
solid
反应适用性
core: gadolinium
reagent type: catalyst
mp
>300 °C
SMILES字符串
CC(C)O[Gd](OC(C)C)OC(C)C
InChI
1S/3C3H7O.Gd/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InChI key
VJLSFXQJAXVOEQ-UHFFFAOYSA-N
应用
在很多不对称催化应用中，应当使用手套箱和 Schlenk 技术防止此稀土催化剂与空气和水分接触，因为这两个因素将对反应结果产生不利影响。用无水溶剂配制该催化剂溶液并立即使用。
用三甲基硅叠氮使内消旋-氮杂环丙烷开环的催化剂。
Catalyst for:
- Enantioselective construction of beta-quaternary carbons via conjugate addition reactions
- Generation of reactive enolates
- Regioselective / stereoselective conjugate addition of cyanide to enones
- Strecker reactions
- Asymmetric ring-opening of meso-aziridines
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Yuhei Fukuta et al.
Journal of the American Chemical Society, 128(19), 6312-6313 (2006-05-11)
An asymmetric ring-opening reaction of meso-aziridines with TMSN3 was developed using a catalyst prepared from Y(OiPr)3 and chiral ligand 2 in a 1:2 ratio. Excellent enantioselectivity was realized from a wide range of substrates with a practical catalyst loading. The
相关内容
Shibasaki's research focuses on novel asymmetric catalytic systems for streamlined synthesis of enantioenriched chiral building blocks.
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