所有图片(3)
About This Item
经验公式（希尔记法）:
C32H40O8Rh2
CAS号:
分子量:
758.47
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
95%
表单
solid
反应适用性
core: rhodium
reagent type: catalyst
reaction type: C-H Activation
mp
>300 °C
SMILES字符串
[Rh][Rh].CC(C)(Cc1cccc(CC(C)(C)C(O)=O)c1)C(O)=O.CC(C)(Cc2cccc(CC(C)(C)C(O)=O)c2)C(O)=O
InChI
1S/2C16H22O4.2Rh/c2*1-15(2,13(17)18)9-11-6-5-7-12(8-11)10-16(3,4)14(19)20;;/h2*5-8H,9-10H2,1-4H3,(H,17,18)(H,19,20);;
InChI key
OBMUTUNJWNQIAJ-UHFFFAOYSA-N
相关类别
一般描述
双[α,α,α′,α′-四甲基-1,3-苯二丙酸铑] 已被确认为高效的C-H 活化催化剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Kristin Williams Fiori et al.
Journal of the American Chemical Society, 129(3), 562-568 (2007-01-18)
Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiomeric 3 degrees centers, displays high
商品
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
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