所有图片(3)
About This Item
线性分子式:
HSC6H4CO2H
CAS号:
分子量:
154.19
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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等级
technical grade
质量水平
方案
90%
表单
solid
mp
215-224 °C (lit.)
官能团
carboxylic acid
SMILES字符串
OC(=O)c1ccc(S)cc1
InChI
1S/C7H6O2S/c8-7(9)5-1-3-6(10)4-2-5/h1-4,10H,(H,8,9)
InChI key
LMJXSOYPAOSIPZ-UHFFFAOYSA-N
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一般描述
4-Mercaptobenzoic acid (4-MBA), also known as 4-Carboxythiophenol or p-Mercaptobenzoic acid, is an aromatic compound used in organic synthesis. 4-MBA promotes the formation of disulfide bonds through its reactive thiol (-SH) group. The sulfur atom in the thiol group is highly nucleophilic, allowing it to attack electrophiles. facilitates the formation of diverse thiol-containing compounds. Additionally, 4-MBA serves as a ligand to form coordination complexes and is utilized for surface functionalization, particularly in creating self-assembled monolayers (SAMs) on metal surfaces.
应用
- 食品掺假检测的SERS底物：采用4-巯基苯甲酸通过生物聚合物层层组装，原位制造AuNP等离子体纸，可作为表面增强拉曼散射(SERS)基底用于食品掺假检测(Viriyakitpattana et al., 2024)。
- 磁性-等离子体纳米粒子的开发：结合激光烧蚀和溶剂热法获得磁性-等离子体纳米粒子，可用于4-巯基苯甲酸为标记分子的多波长SERS。说明纳米颗粒合成的多样性(Talaikis et al., 2023)。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Chitosan-4-mercaptobenzoic acid: synthesis and characterization of a novel thiolated chitosan
Millotti et al.
Journal of Materials Chemistry, 20, 2432-2440 (2010)
Electrochemical and infrared spectroscopy studies of 4-mercaptobenzoic acid SAMs on gold surfaces
Rosendahl et al.
Electrochimica Acta, 53, 6759-6767 (2008)
Coordination chemistry of 3-and 4-mercaptobenzoate ligands: versatile hydrogen-bonding isomers of the thiosalicylate (2-mercaptobenzoate) ligand
Tiekink et al.
Coordination Chemistry Reviews, 341, 19-52 (2017)
A theoretical study of 4-Mercaptobenzoic acid assembled on Ag for surface-enhanced raman scattering applications
Mhlanga et al.
Materials Today Communications, 26, 101698-101698 (2021)
Christopher J Ackerson et al.
Bioconjugate chemistry, 21(2), 214-218 (2010-01-27)
By adjustment of solvent conditions for synthesis, virtually monodisperse 4-mercaptobenzoic acid (p-MBA) monolayer-protected gold nanoparticles, 2 and 3 nm in diameter, were obtained. Large single crystals of the 2 nm particles could be grown from the reaction mixture. Uniformity was
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