所有图片(2)
About This Item
经验公式（希尔记法）:
C16H23IO4
CAS号:
分子量:
406.26
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
97%
形式
solid
反应适用性
reagent type: catalyst
reaction type: C-H Activation
reagent type: oxidant
mp
104-109 °C
SMILES字符串
CC(C)(C)C(=O)O[I](OC(=O)C(C)(C)C)c1ccccc1
InChI
1S/C16H23IO4/c1-15(2,3)13(18)20-17(12-10-8-7-9-11-12)21-14(19)16(4,5)6/h7-11H,1-6H3
InChI key
DZKPLZUSZXYHFB-UHFFFAOYSA-N
应用
Rh2(esp)2：C-H氨基化非常有效的选择性催化剂
用于以下反应的试剂：
用于以下反应的试剂：
- Rh催化氨基甲酸丙酯CH胺化，Ru催化环羰基化合成α、β-不饱和-γ-内酰胺
- 钯催化的二胺反应
- 铑催化的烯丙基化和环化反应制备功能化双环杂环化合物
- 铜催化氨基甲酸分子内氨基乙酰氧基化化合成萘酚和吡咯烷衍生物
- 芳烃的 C-H 酰氧基化
- 高价碘氧化剂
与 Rh2(esp)2 催化剂 (662623) 共同用于 C-H 键胺化的高价碘试剂。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Dzmitry M Zubrytski et al.
Molecules (Basel, Switzerland), 26(1) (2021-01-06)
Oxidative fragmentation of tertiary cyclopropanols with phenyliodine(III) dicarboxylates in aprotic solvents (dichloromethane, chloroform, toluene) produces mixed anhydrides. The fragmentation reaction is especially facile with phenyliodine(III) reagents bearing electron-withdrawing carboxylate ligands (trifluoroacetyl, 2,4,6-trichlorobenzoyl, 3-nitrobenzoyl), and affords 95-98% yields of the corresponding
Kristin Williams Fiori et al.
Journal of the American Chemical Society, 129(3), 562-568 (2007-01-18)
Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiomeric 3 degrees centers, displays high
商品
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
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