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Merck
CN

661384

Sigma-Aldrich

2-碘酰基苯甲酸

contains stabilizer, 45 wt. % (IBX)

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别名:
2-碘酰苯甲酸, SIBX
经验公式(希尔记法):
C7H5IO4
CAS号:
分子量:
280.02
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

形式

solid

质量水平

包含

stabilizer

反应适用性

reagent type: oxidant

浓度

45 wt. % (IBX)

SMILES字符串

OI1(=O)OC(=O)c2ccccc12

InChI

1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)

InChI key

CQMJEZQEVXQEJB-UHFFFAOYSA-N

应用

是 IBX 的稳定形态 (SIBX),不具有 IBX 的任何易爆性,同时保持了出色的反应性和选择性。
用于在 DMSO 存在的条件下将芴甲氧羰基保护的氨基醇氧化为相应的氨基醛的试剂。

其他说明

本品在苯甲酸和间苯二甲酸中稳定。

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3

靶器官

Lungs, Respiratory system

补充剂危害

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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