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Merck
CN

659452

1-金刚烷硫醇

95%

别名:

1-AD, 1-AdSH, 1-AdmSH

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关于此项目

经验公式(希尔记法):
C10H16S
化学文摘社编号:
分子量:
168.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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产品名称

1-金刚烷硫醇, 95%

InChI

1S/C10H16S/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9,11H,1-6H2/t7-,8+,9-,10-

SMILES string

SC12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI key

ADJJLNODXLXTIH-CHIWXEEVSA-N

assay

95%

form

solid

mp

99-106 °C

Quality Level

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Application

AT可用于修饰叶酸基乙二醇马来酰亚胺,其可用于开发金纳米棒(AuNR)基混合物,用于抗癌药的时空递送。它也可以和1-十八硫醇一起使用,在钯/氧化铝 (Pd/Al2O3) 上形成SAM,用作受控型催化剂等。
用于制备1-金刚烷基硫代唾液苷的试剂,与单糖和寡糖一起在三酸NIS处理中进行糖基化。

General description

1-金刚烷硫醇(AT)是一种基于庞大笼状烃的硫醇,其主链中没有自由旋转的构型。它通过密集堆积结构连接表面原子,形成一种自组装单层(SAM)。

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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分析证书(COA)

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A dual wavelength-activatable gold nanorod complex for synergistic cancer treatment
Pacardo DB, et al.
Nanoscale, 7(28), 12096-12103 (2015)
Thermal study and structural characterization of self-assembled monolayers generated from diadamantane disulfide on Au (1 1 1)
Azzam W, et al.
Applied Surface Science, 257(8), 3739-3747 (2011)
Control of Pd catalyst selectivity with mixed thiolate monolayers
Lien C and Medlin JW
J. Catal., 339(28), 38-46 (2016)
Arrelaine A Dameron et al.
Journal of the American Chemical Society, 127(24), 8697-8704 (2005-06-16)
We have designed monolayers with weak intermolecular interactions for use as placeholders in intelligent self- and directed-assembly. We have shown that these 1-adamantanethiolate monolayers are labile with respect to displacement by exposing them to dilute solutions of alkanethiols. These self-assembled
David Crich et al.
The Journal of organic chemistry, 72(20), 7794-7797 (2007-09-11)
Novel 1-adamantanylthio sialosides were synthesized and coupled to acceptors under NIS/TfOH promotion conditions. These donors showed higher reactivity than the phenylthio sialosides and could be activated by NIS/TfOH in nitrile solvents at -78 degrees C to afford improved alpha-sialylations. With

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