质量水平
检测方案
95%
形式
solid
mp
99-106 °C
SMILES字符串
SC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C10H16S/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9,11H,1-6H2/t7-,8+,9-,10-
InChI key
ADJJLNODXLXTIH-CHIWXEEVSA-N
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一般描述
1-金刚烷硫醇(AT)是一种基于庞大笼状烃的硫醇,其主链中没有自由旋转的构型。它通过密集堆积结构连接表面原子,形成一种自组装单层(SAM)。
应用
AT可用于修饰叶酸基乙二醇马来酰亚胺,其可用于开发金纳米棒(AuNR)基混合物,用于抗癌药的时空递送。它也可以和1-十八硫醇一起使用,在钯/氧化铝 (Pd/Al2O3) 上形成SAM,用作受控型催化剂等。
用于制备1-金刚烷基硫代唾液苷的试剂,与单糖和寡糖一起在三酸NIS处理中进行糖基化。
警示用语:
Danger
危险声明
危险分类
Acute Tox. 3 Oral - Eye Irrit. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Thermal study and structural characterization of self-assembled monolayers generated from diadamantane disulfide on Au (1 1 1)
Applied Surface Science, 257(8), 3739-3747 (2011)
A dual wavelength-activatable gold nanorod complex for synergistic cancer treatment
Nanoscale, 7(28), 12096-12103 (2015)
Control of Pd catalyst selectivity with mixed thiolate monolayers
J. Catal., 339(28), 38-46 (2016)
The Journal of organic chemistry, 72(20), 7794-7797 (2007-09-11)
Novel 1-adamantanylthio sialosides were synthesized and coupled to acceptors under NIS/TfOH promotion conditions. These donors showed higher reactivity than the phenylthio sialosides and could be activated by NIS/TfOH in nitrile solvents at -78 degrees C to afford improved alpha-sialylations. With
Journal of the American Chemical Society, 127(24), 8697-8704 (2005-06-16)
We have designed monolayers with weak intermolecular interactions for use as placeholders in intelligent self- and directed-assembly. We have shown that these 1-adamantanethiolate monolayers are labile with respect to displacement by exposing them to dilute solutions of alkanethiols. These self-assembled
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