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Merck
CN

658693

Sigma-Aldrich

Pd(II) EnCat® BINAP30

extent of labeling: 0.39 mmol/g Pd loading, BINAP 0.25, Pd 1.0

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别名:
聚脲基质微囊化乙酸钯和 BINAP
MDL编号:
UNSPSC代码:
12352300
NACRES:
NA.22

组成

BINAP, 0.25
Pd, 1.0

质量水平

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

标记范围

0.39 mmol/g Pd loading

一般描述

It is Pd EnCat® catalyst, wherein palladium acetate and 1,1′-binaphthalene-2,2′-diylbis(diphenylphosphine) (BINAP) are microencapsulated within a polyurea matrix, which prevents palladium leaching.

特点和优势

The advantage of Pd EnCat® catalysts are:
  • Low residual metal levels in crude product.
  • Easy recovery of catalyst.
  • Compatibility of immobilized metal with various ligands to effect C–C bond forming reactions.
  • Safer and easier to handle than Pd/C for hydrogenation.
  • Efficiency and economy gains through recovery and recycling.

法律信息

Pd Encat 技术已申请国际专利,包括 PCT/GB 02/03135。
EnCat is a registered trademark of Reaxa Ltd.

警示用语:

Danger

危险分类

Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Sol. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation

靶器官

Nervous system

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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