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Merck
CN

654213

Sigma-Aldrich

2-甲基吡啶硼烷复合物

95%

别名:

2-吡啶硼烷复合物

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About This Item

CAS号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

95%

形式

solid

反应适用性

reagent type: reductant

储存温度

2-8°C

SMILES字符串

CC1=NC=CC=C1.B

InChI

1S/C6H7N.B/c1-6-4-2-3-5-7-6;/h2-5H,1H3;

InChI key

QHXLIQMGIGEHJP-UHFFFAOYSA-N

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一般描述

2-甲基吡啶硼烷络合物是还原剂氰基硼氢化钠的无毒替代物。

应用

2-甲基吡啶硼烷络合物溶液被用作还原剂,通过还原胺化反应来标记低聚糖。 它可用于以下研究:
  • 通过还原肟醚而合成烷氧基胺衍生物。
  • C1-C10醛 2,4-二硝基苯腙的还原 胺化反应。
  • 各种三氟甲基化氨基化合物的合成。
  • 作为还原胺化的替代试剂。
环保型还原剂

反应物用于:
还原胺化反应
通过还原烷基化反应保护氨基酸衍生物的N-苄基
还原烷氧基胺化反应

象形图

FlameExclamation mark

警示用语:

Danger

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Trifluoroacetaldehyde: A useful industrial bulk material for the synthesis of trifluoromethylated amino compounds.
Mimura H, et al.
Journal of Fluorine Chemistry, 131(4), 477-486 (2010)
Maaike M Appeldoorn et al.
Carbohydrate research, 381, 33-42 (2013-09-24)
In order to use corn fiber as a source for bioethanol production the enzymatic hydrolysis of the complex glucuronoarabinoxylans present has to be improved. Several oligosaccharides present in the supernatant of mild acid pretreated and enzymatically saccharified corn fiber that
Sato, S. et al
Tetrahedron, 60, 7899-7899 (2004)
Shigehisa Uchiyama et al.
Analytical chemistry, 81(1), 485-489 (2008-12-06)
A new method for the determination of carbonyls in air using 2,4-dinitrophenylhydrazine (DNPH) has been developed. The traditional method for the measurement of carbonyl compounds, using DNPH to form the corresponding 2,4-dinitrophenylhydrazone (DNPhydrazone) derivatives, is subject to analytical errors because
One-pot synthesis of alkoxyamine derivatives by reductive alkoxyamination with a 2-picoline-borane complex.
Kawase Y , et al.
Heterocycles, 78(2), 463-470 (2009)

商品

2-甲基吡啶-甲硼烷(pic-BH3)是还原胺的一个出色的替代试剂。

2-picoline-borane (pic-BH3) is an excellent alternative reagent for reductive aminations.

Learn about the applications of chiral oxazaborolidinium ions (COBIs) as Lewis acid catalysts in different asymmetric reactions such as cyclopropanation, epoxidation, and radical reactions along with details of their catalytic action.

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