推荐产品
蒸汽压
8.09 psi ( 20 °C)
质量水平
方案
≥99%
折射率
n20/D 1.372 (lit.)
沸点
36-38 °C (lit.)
mp
−140 °C (lit.)
密度
0.675 g/mL at 25 °C (lit.)
官能团
amine
SMILES字符串
CCN(C)C
InChI
1S/C4H11N/c1-4-5(2)3/h4H2,1-3H3
InChI key
DAZXVJBJRMWXJP-UHFFFAOYSA-N
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应用
N , N -二甲基乙胺 (DMEA) 一般用于制备水溶性季铵盐。促进六甲基二硅氮化锂 (LiHMDS) 介导的高度取代芳基酮的烯醇化。 此外，DMEA 还在合成化学中用作有机溶剂。
警示用语：
Danger
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-18.4 °F - closed cup
闪点(°C)
-28 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles
法规信息
危险化学品
Sodium Diisopropylamide in Tetrahydrofuran: Selectivities, Rates, and Mechanisms of Alkene Isomerizations and Diene Metalations.
Algera RF, et al.
Journal of the American Chemical Society, 139(33), 11544-11549 (2017)
Sodium Diisopropylamide in N, N-Dimethylethylamine: Reactivity, Selectivity, and Synthetic Utility.
Ma Y, et al.
The Journal of Organic Chemistry, 81(22), 11312-11315 (2016)
Lithium Hexamethyldisilazide-Mediated Enolization of Highly Substituted Aryl Ketones: Structural and Mechanistic Basis of the E/Z Selectivities.
Mack KA, et al.
Journal of the American Chemical Society, 139(35), 12182-12189 (2017)
A theophylline based copper N-heterocyclic carbene complex: synthesis and activity studies in green media.
Szadkowska A, et al.
Royal Society of Chemistry Advances, 6(50), 44248-44253 (2016)
Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-Carbon Olefins via Enol Tosylation and Suzuki-Miyaura Coupling.
Li BX, et al.
Journal of the American Chemical Society, 139(31), 10777-10783 (2017)
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